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- W2092192854 abstract "The synthesis of 4-hydroxy-3-[(1S)-1,2,2-trimethylcyclopentyl]benzaldehyde [(−)-α-formylherbertenol 1], a herbertane-type sesquiterpene isolated from the leafy liverwort Herberta adunca, from β-cyclogeraniol is described. The synthesis is based on the previously described preparation of an enantiopure 1,2,2-trimethylcyclopentane synthon from which the characteristic aromatic moiety of 1 is elaborated, using a Robinson annulation and a palladium-catalysed methoxycarbonylation of an aryl triflate as key synthetic steps. The synthesis of the natural sesquiterpene (−)-α-herbertenol, also a natural sequiterpene, using the same methodology is also described." @default.
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- W2092192854 date "2000-04-01" @default.
- W2092192854 modified "2023-09-27" @default.
- W2092192854 title "Enantioselective synthesis of herbertane sesquiterpenes: synthesis of (−)-α-formylherbertenol" @default.
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- W2092192854 doi "https://doi.org/10.1016/s0957-4166(00)00079-3" @default.
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