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- W2092198150 abstract "The fluorescence quenching effect of emodin (EMO) on the derivatives of p-tert-butyl-calix[4]arene with o-phenanthroline (TBCP) in 1.0% hexadecyl trimethyl ammonium bromide (CTAB) medium was investigated. The fluorescence of TBCP was quenched by EMO due to the formation of the weak fluorescent inclusion complex (EOM-TBCP), and the fluorescence quenching (ΔF = FTBCP–FEMO–TBCP) was sensitized in CTAB. Under the optimal conditions, the linear range of calibration curve for the determination of EMO was 1.17–23.40 μg/mL. The detection limit estimated and RSD was 0.34 μg/mL, 3.63% (n = 3, c = 4.74 μg/mL). The quantum yield Yu of TBCP was approximately 2.0 times higher in the presence of CTAB than that in the absence of CTAB. The method has been applied for the determination of EMO in samples with satisfactory results." @default.
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- W2092198150 date "2012-09-01" @default.
- W2092198150 modified "2023-10-16" @default.
- W2092198150 title "Determination of emodin by hexadecyl trimethyl ammonium bromide sensitized fluorescence quenching method of the derivatives of calix[4]arene" @default.
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- W2092198150 doi "https://doi.org/10.1016/j.saa.2012.04.084" @default.
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