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- W2092202012 abstract "S4N4 · SO3 wurde durch Reaktion von S4N4 mit SO3 in CH2Cl2 und über eine lösungsmittelfreie Umsetzung von S4N4 mit Fluorsulfonsäureanhydrid erhalten. Eine Einkristall-Röntgen-Strukturanalyse lieferte die Struktur des Adduktes. Der „Käfig”︁ des freien S4N4 faltet analog der Struktur des S4N4 · SbCl5 in eine deformierte Sattelkonformation mit näherungsweise Cs-Symmetrie um. Die SN-Bindungsabstände im S4N4-Ring Variieren von 1,51 bis 1,69 Å. Die Cs-Symmetrie wird deutlich durch die Stellung der SO3-Gruppe durchbrochen. In der Kristallstruktur mit einer monoklinen Elementarzelle der Raumgruppe P21/n ordnen sich die Moleküle in Säulen mit pseudohexagonaler gegenseitiger Anordnung. Synthesis and X-ray Structure Analysis of the Addition Compound of Sulfurtrioxide and Tetrasulfurtetranitride (S4N4· SO3) S4N4 · SO3 was obtained by reaction of S4N4 with SO3 in CH2Cl2 and by solvent free reaction of S4N4 with Fluorosulfonic acid anhydride. The structure of the adduct could be determined by single crystal X-ray structure analysis. The “cage” of the S4N4 is analogous to the structure of S4N4 · SbCl5 reconvoluted into a deformated saddle conformation with nearly Cs-symmetry. The SN bond lengths in the S4N4 ring vary from 1.51 to 1.69 Å. The Cs-symmetry is significantly disturbed by the position of the SO3 group. In the crystal structure with monoclinic unit cell of space group P21/n the molecules are packed into columns, which are arranged pseudohexagonally." @default.
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- W2092202012 date "1978-05-01" @default.
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- W2092202012 title "Synthese und R�ntgenstrukturanalyse des Additionsproduktes von Schwefeltrioxid an Tetraschwefeltetranitrid (S4N4� SO3)" @default.
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- W2092202012 doi "https://doi.org/10.1002/zaac.19784400112" @default.
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