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• W2092202359 endingPage "2605" @default.
• W2092202359 startingPage "2599" @default.
• W2092202359 abstract "Combinations of homogeneous Cu salts and TEMPO have emerged as practical and efficient catalysts for the aerobic oxidation of alcohols. Several closely related catalyst systems have been reported, which differ in the identity of the solvent, the presence of 2,2'-bipyridine as a ligand, the identity of basic additives, and the oxidation state of the Cu source. These changes have a significant influence on the reaction rates, yields, and substrate scope. In this report, we probe the mechanistic basis for differences among four different Cu/TEMPO catalyst systems and elucidate the features that contribute to efficient oxidation of aliphatic alcohols." @default.
• W2092202359 created "2016-06-24" @default.
• W2092202359 creator A5018364473 @default.
• W2092202359 creator A5056767355 @default.
• W2092202359 creator A5074617275 @default.
• W2092202359 date "2013-10-22" @default.
• W2092202359 modified "2023-09-26" @default.
• W2092202359 title "Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems" @default.
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• W2092202359 doi "https://doi.org/10.1021/cs400689a" @default.
• W2092202359 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3925889" @default.
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• W2092202359 hasPublicationYear "2013" @default.
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