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- W2092203463 abstract "A detailed study of bimetallic thiophene-bridged complexes, formed by coordination of a second metal fragment to a transition-metal-inserted thiophene complex, is reported. The bonding interactions between mononuclear metallathiacycles and a second metal center, the effects of coordination of a second metal center on the M−C and M−S bonds of the heterocycle, the stability of bimetallic thiophene-bridged complexes, and their possible role in homogeneous desulfurization reactions are addressed. Fenske−Hall molecular orbital calculations on the square-planar, transition-metal-inserted benzothiophene (BT) complex (dippe)Ni(η2-S,C-BT) (6) (dippe = (i-Pr2PCH2)2) and the bimetallic bridged adduct [(dippe)Ni]2(η-BT) (7) show that the [(dippe)Ni] fragment coordinates to 6 via a σ interaction to the sulfur atom and a π-bonding/back-bonding interaction to the C−C double bond of the heterocycle. Both interactions are weak, and coordination of the second [(dippe)Ni] fragment has little effect on the electronic structu..." @default.
- W2092203463 created "2016-06-24" @default.
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- W2092203463 date "2000-04-29" @default.
- W2092203463 modified "2023-09-25" @default.
- W2092203463 title "The Role of Bimetallic Thiophene-Bridged Complexes in Homogeneous Desulfurization Reactions" @default.
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- W2092203463 doi "https://doi.org/10.1021/om991005b" @default.
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