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- W2092205198 abstract "Using molecular dynamics (MD) simulations, we demonstrated that charged carbon nanotubes (CNTs) can be applied as nanoelectrodes for separation of Na+ and Cl− ions from NaCl solution and subsequent desalination in a typical nanoscale lab-on-a-chip system. Three different surface charge densities (σ = 0.84, 1.68 and 3.36 C/m2) were exerted on nanotubes. Our results show that under such electrical external field, positive ions (Na+) are transported to negatively charged CNT and vice versa. This external field leads to ion pair break-up and consequent desalination; although, the amount of separation depends on the magnitude of applied charge. Interestingly, applying electrical charges on CNTs induces hydrophilic nature in them which is entirely contrary to their previous hydrophobic nature. Moreover, depending on the type of applied charge, positive or negative, water molecules orient differently relative to CNT electrodes. Extra investigations on Na+ ions reveal a basic disruption in their hydration shell which occurs upon the presence of external field. This study provides us the potential application of CNTs as efficient nanomaterials for desalination purposes in nanoscale dimensions." @default.
- W2092205198 created "2016-06-24" @default.
- W2092205198 creator A5021006061 @default.
- W2092205198 creator A5061483385 @default.
- W2092205198 date "2011-08-01" @default.
- W2092205198 modified "2023-10-01" @default.
- W2092205198 title "Ion-separation and water-purification using single-walled carbon nanotube electrodes" @default.
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- W2092205198 doi "https://doi.org/10.1016/j.desal.2011.04.028" @default.
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