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- W2092240429 abstract "the fragment indicates the significant conjugation. The other bond lengths and angles are quite typical, thus they don't call for further discussion. In the title compound, cyclohexanone ring adopts a half-chair conformation with the maximum deviation being 0.304(2) Â for CI5. The naphthyl and cyclohexenone moieties are not coplanar. The dihedral angle between the leastsquares planes is 77.72(8)°, which is slightly larger than its relative structures because of the more bulky naphthyl group, but much bigger than its acyclic /J-enaminone [4,5]. Unlike the acyclic /3-enaminones [4,5], the formation of the intramolecular hydrogen bond is forbidden [6] because of the torsional strain in the cyclic compounds. Thus, the secondary amine can only give rise" @default.
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- W2092240429 date "2009-04-01" @default.
- W2092240429 modified "2023-09-26" @default.
- W2092240429 title "Crystal structure of 5,5-dimethyl-3-(naphthalen-lylamino) cyclohex-2-enone, C18H19NO" @default.
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- W2092240429 doi "https://doi.org/10.1524/ncrs.2009.224.14.435" @default.
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