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- W2092268185 abstract "Abstract Syntheses of a series of 2-deoxy-L-ribonolactones modified at C-3 with groups isosteric to the 3-O-acyl moiety of the parent 3-O-tetradecanoyl-2-deoxy-L-ribonolactone (1) are reported. Lipophilicity of the molecules was kept constant by maintaining invariant the length of the aliphatic chain. Compound 5 was identified as having an affinity equal to that of 1 in a competitive binding assay that measured the ability of the ligands to displace [3H]-phorbol-12,13-dibutyrate from PK-C. The reverse ester function in 5 makes this compound more stable than 1 by preventing β-elimination. Other changes in 1 led to a reduction in affinity." @default.
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- W2092268185 date "1994-06-01" @default.
- W2092268185 modified "2023-09-23" @default.
- W2092268185 title "Conformationally constrained analogues of dag .8. Changes in PK-C binding affinity produced by isosteric groups of the 3-O-acyl function in 2-deoxy-L-ribonolactones" @default.
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- W2092268185 doi "https://doi.org/10.1016/s0960-894x(01)80364-4" @default.
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