FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092286867> ?p ?o ?g. }

• W2092286867 endingPage "14761" @default.
• W2092286867 startingPage "14751" @default.
• W2092286867 abstract "To elucidate the dependence of the nonlinear optical (NLO) response on the conformation of triply branched derivatives, a new series of D-π-A dendrimers has been synthesized. A combined approach of experiments (UV−vis and EOA measurements) and computational predictions (semiempirical and ab initio) was applied both on the dendrimers and on the corresponding single-strand chromophores. It has been shown that depending on the surrounding media the NLO activity of a flexible dendrimer can be very different. Two limiting cases are proposed: (i) the dendrimer resembles a solution of the corresponding single-strand chromophores with about 3-fold concentration, where the hyperpolarizability is the sum of the effect of three noninteracting single-strand subunits (“independent chromophores” limit); (ii) the dendrimers show nearly parallel or helical alignments of the single-strand subunits. Because of this change of conformation the NLO activity can be enhanced up to nine times the value of the “independent chromophores” limit and, thus, are more than a single strand chromophore. Conformers of dendrimers with interacting single-strand chromophores have been identified experimentally in nonpolar solutions by the EOA spectroscopy and possible structures have been revealed by numerical calculations, which could moreover show the tendency of the effects on the hyperpolarizability due to structural changes of the flexible dendritic architecture. Implications for future research developments are given to implement the “more than three times” concept." @default.
• W2092286867 created "2016-06-24" @default.
• W2092286867 creator A5009455111 @default.
• W2092286867 creator A5013135597 @default.
• W2092286867 creator A5013668084 @default.
• W2092286867 creator A5025197984 @default.
• W2092286867 creator A5040766355 @default.
• W2092286867 creator A5043732951 @default.
• W2092286867 creator A5046207167 @default.
• W2092286867 creator A5050836020 @default.
• W2092286867 creator A5051363890 @default.
• W2092286867 creator A5057282533 @default.
• W2092286867 creator A5087703591 @default.
• W2092286867 date "2008-10-31" @default.
• W2092286867 modified "2023-10-01" @default.
• W2092286867 title "Three-Branched Dendritic Dipolar Nonlinear Optical Chromophores, More than Three Times a Single-Strand Chromophore?" @default.
• W2092286867 cites W1963575591 @default.
• W2092286867 cites W1966182479 @default.
• W2092286867 cites W1971191274 @default.
• W2092286867 cites W1977747032 @default.
• W2092286867 cites W1979682426 @default.
• W2092286867 cites W1987866753 @default.
• W2092286867 cites W1988904684 @default.
• W2092286867 cites W1991624968 @default.
• W2092286867 cites W1991968263 @default.
• W2092286867 cites W2002436135 @default.
• W2092286867 cites W2006144122 @default.
• W2092286867 cites W200615860 @default.
• W2092286867 cites W2008206065 @default.
• W2092286867 cites W2014443975 @default.
• W2092286867 cites W2019752409 @default.
• W2092286867 cites W2023271753 @default.
• W2092286867 cites W2024355976 @default.
• W2092286867 cites W2029821429 @default.
• W2092286867 cites W2031874354 @default.
• W2092286867 cites W2032192059 @default.
• W2092286867 cites W2036950690 @default.
• W2092286867 cites W2039024571 @default.
• W2092286867 cites W2044490585 @default.
• W2092286867 cites W2060306489 @default.
• W2092286867 cites W2068617439 @default.
• W2092286867 cites W2070004619 @default.
• W2092286867 cites W2076166510 @default.
• W2092286867 cites W2079473982 @default.
• W2092286867 cites W2081121524 @default.
• W2092286867 cites W2083010228 @default.
• W2092286867 cites W2084599106 @default.
• W2092286867 cites W2088125890 @default.
• W2092286867 cites W2088222553 @default.
• W2092286867 cites W2090082588 @default.
• W2092286867 cites W2095068910 @default.
• W2092286867 cites W2109882423 @default.
• W2092286867 cites W2132981561 @default.
• W2092286867 cites W2143981217 @default.
• W2092286867 cites W2221024888 @default.
• W2092286867 cites W2321426663 @default.
• W2092286867 cites W2949582269 @default.
• W2092286867 cites W3004465863 @default.
• W2092286867 cites W4239680701 @default.
• W2092286867 cites W4242591046 @default.
• W2092286867 doi "https://doi.org/10.1021/jp802369c" @default.
• W2092286867 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18973370" @default.
• W2092286867 hasPublicationYear "2008" @default.
• W2092286867 type Work @default.
• W2092286867 sameAs 2092286867 @default.
• W2092286867 citedByCount "20" @default.
• W2092286867 countsByYear W20922868672012 @default.
• W2092286867 countsByYear W20922868672013 @default.
• W2092286867 countsByYear W20922868672014 @default.
• W2092286867 countsByYear W20922868672016 @default.
• W2092286867 countsByYear W20922868672017 @default.
• W2092286867 countsByYear W20922868672018 @default.
• W2092286867 countsByYear W20922868672019 @default.
• W2092286867 countsByYear W20922868672020 @default.
• W2092286867 countsByYear W20922868672022 @default.
• W2092286867 crossrefType "journal-article" @default.
• W2092286867 hasAuthorship W2092286867A5009455111 @default.
• W2092286867 hasAuthorship W2092286867A5013135597 @default.
• W2092286867 hasAuthorship W2092286867A5013668084 @default.
• W2092286867 hasAuthorship W2092286867A5025197984 @default.
• W2092286867 hasAuthorship W2092286867A5040766355 @default.
• W2092286867 hasAuthorship W2092286867A5043732951 @default.
• W2092286867 hasAuthorship W2092286867A5046207167 @default.
• W2092286867 hasAuthorship W2092286867A5050836020 @default.
• W2092286867 hasAuthorship W2092286867A5051363890 @default.
• W2092286867 hasAuthorship W2092286867A5057282533 @default.
• W2092286867 hasAuthorship W2092286867A5087703591 @default.
• W2092286867 hasConcept C121332964 @default.
• W2092286867 hasConcept C147597530 @default.
• W2092286867 hasConcept C158622935 @default.
• W2092286867 hasConcept C159467904 @default.
• W2092286867 hasConcept C173523689 @default.
• W2092286867 hasConcept C178790620 @default.
• W2092286867 hasConcept C185592680 @default.
• W2092286867 hasConcept C18705241 @default.
• W2092286867 hasConcept C188027245 @default.
• W2092286867 hasConcept C192468462 @default.
• W2092286867 hasConcept C192562407 @default.

• next