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- W2092294313 abstract "Abstract The third-order nonlinear optical susceptibility, χ (3) xxxx , of solutions of Co(III) and Ni(II) complexes of o -aminobenzenethiol, o -NH 2 C 6 H 4 SH, were measured by degenerate four-wave mixing at 0.164 μm. In solution, the deprotonation of Ni( o -NH 2 C 6 H 4 S) 2 was found to occur in the presence of air and was accelerated by mild warming, yielding Ni( o -NHC 6 H 4 S) 2 . This complex has a large 〈λ xxxx 〉 = 2 × 10 −31 esu with an estimated χ (3) xxxx on the order of 2 × 10 −9 esu. A low-energy dd transition has been measured at 1.1 μm for the nickel complex and may be responsible for its enhanced third-order optical nonlinearity." @default.
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- W2092294313 date "1991-04-01" @default.
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- W2092294313 title "Nonlinear optical studies on transition metal complexes of o-aminobenzenethiol" @default.
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- W2092294313 doi "https://doi.org/10.1016/0009-2614(91)90295-k" @default.
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