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• W2092300911 endingPage "166" @default.
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• W2092300911 abstract "The clusters [M3(CO)12], (M  Ru or Fe), [Fe2Ru(CO)12], [FeRu2(C0)12], [H4Ru4(CO)12] and [H2M′M3(CO)13] (M  Ru, M′  Fe or Ru) have been tested as homogeneous catalysts for the hydrogenation of C2Ph2 and isomerization of cis-stilbene. The effect of the cluster stoichiometry, of dihydrogen and of the substrate/cluster ratio have been evaluated. There is evidence of competition between dihydrogen, which favours the formation of catalytically active hydrides or “metal fragments”, and C2Ph2, which favours metal-fragment condensation to give alkyne-substituted clusters; with the exception of [H2Ru3(CO)9C2Ph2], these derivatives are stable by-products and react slowly with dihydrogen, giving only small amounts of hydrogenation products. The alkyne-substituted derivatives found in the hydrogenation solutions are the reported products of the reactions of iron, ruthenium or iron-ruthenium carbonyl clusters with C2Ph2 under dinitrogen; however, there are differences in the yields. Moreover, in the reactions of [H2Ru4(CO)13] or [H2FeRu3(CO)13], a new derivative was obtained; this was characterized spectroscopically as a third isomer of [Ru3(CO)8(C2Ph2)2]." @default.
• W2092300911 created "2016-06-24" @default.
• W2092300911 creator A5049446594 @default.
• W2092300911 creator A5057616848 @default.
• W2092300911 date "1993-04-01" @default.
• W2092300911 modified "2023-10-17" @default.
• W2092300911 title "Heterometallic clusters in homogeneous catalysis. Hydrogenation of diphenylacetylene and isomerization of cis-stilbene in the presence of [Fe2Ru(CO)12], [FeRu2(CO)12], [H2FeRu3(CO)13], [H2Ru4(CO)13], and related compounds. Identification of organometallic complexes and a discussion of their role" @default.
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• W2092300911 doi "https://doi.org/10.1016/0022-328x(93)80080-u" @default.
• W2092300911 hasPublicationYear "1993" @default.
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