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- W2092336265 abstract "Abstract Fourier transform ion cyclotron resonance (FTICR) spectroscopic methods have been applied to examine the gas phase reactions of the metal carbonyl anions [metal(CO) 4 ] − , metalCr, Mn; [metal(CO) 3 ] − , metalCr, Mn, Fe; and [metal(CO) 2 ] − , metalFe, Ni with 13 C-labelled carbonyl sulfide. Measurements of temporal variations of ionic product distributions have allowed mechanisms to be proposed to account for the formation of both carbonylated and decarbonylated metal-S bonded ionic reaction products which derive from 13 CS cleavages in [(CO) x ·metal·η 2 -S 13 CO] − intermediates." @default.
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- W2092336265 date "1992-04-01" @default.
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- W2092336265 title "Gas-phase chemistry of first transition series carbonyl metallate ions: reactions with 13C-labelled carbonyl sulfide" @default.
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- W2092336265 doi "https://doi.org/10.1016/s0020-1693(00)85820-x" @default.
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