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- W2092336760 abstract "The synthesis, X-ray structure and magnetochemical properties of the one-dimensional polymeric bicinate (bic−) manganese complex {[Mn(bic)Cl]2·2(H2O)}n are reported. Each manganese ion has distorted octahedral coordination geometry. Bicine is a pentadentate ligand using one nitrogen, and four oxygen atoms to coordinate to the MnII ion. The two hydroxyl groups are not deprotonated and the carboxylate moiety of the bic− ligand ion is a bridge leading to a one-dimensional chain. The water molecules are not coordinated to the MnII ions, but are involved in hydrogen-bonding interactions with the chain. Only weak pairwise antiferromagnetic exchange interactions (J = −0.30 cm−1) are found within the chain complex due to the carboxylate bridges." @default.
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- W2092336760 date "1997-01-01" @default.
- W2092336760 modified "2023-09-24" @default.
- W2092336760 title "One-dimensional polymeric bicinate manganese complex" @default.
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- W2092336760 doi "https://doi.org/10.1016/s0277-5387(97)00073-9" @default.
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