FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092366734> ?p ?o ?g. }

• W2092366734 endingPage "182" @default.
• W2092366734 startingPage "176" @default.
• W2092366734 abstract "Abstract A new simple route to (+)‐ cis ‐2‐methyl‐4‐propyl‐1,3‐oxathiane , the main component responsible of the passion fruit aroma is shown. Such a procedure consists in the sequence of the asymmetric conjugated addition of a thiol to trans ‐2‐hexenal/cleavage of sulfide moiety, which allows to prepare, in only two steps, its immediate precursor, ( R )‐3‐mercaptohexan‐1‐ol. Various procedures have been investigated for both the steps, using benzyl and tert ‐butyl mercaptan as thiols. The best results have been achieved in the addition of benzyl thiol to trans ‐2‐hexenal mediated by a proline‐derived organocatalyst, followed by debenzylation with sodium naphthalenide, affording ( R )‐3‐mercaptohexan‐1‐ol with 84% e.e. and a yield much higher (32%) than that previously reported (8.5%). Chirality, 2009. © 2008 Wiley‐Liss, Inc." @default.
• W2092366734 created "2016-06-24" @default.
• W2092366734 creator A5036867911 @default.
• W2092366734 creator A5059666829 @default.
• W2092366734 creator A5064837553 @default.
• W2092366734 date "2008-08-12" @default.
• W2092366734 modified "2023-10-17" @default.
• W2092366734 title "A new efficient enantioselective synthesis of (+)-<i>cis</i>-2-methyl- 4-propyl-1,3-oxathiane, a valuable ingredient for the aroma of passion fruit" @default.
• W2092366734 cites W1964943599 @default.
• W2092366734 cites W1965054534 @default.
• W2092366734 cites W1966145339 @default.
• W2092366734 cites W1975885494 @default.
• W2092366734 cites W1981129731 @default.
• W2092366734 cites W1981398154 @default.
• W2092366734 cites W1983701633 @default.
• W2092366734 cites W1995137435 @default.
• W2092366734 cites W2007468072 @default.
• W2092366734 cites W2009742246 @default.
• W2092366734 cites W2014375076 @default.
• W2092366734 cites W2023398407 @default.
• W2092366734 cites W2043938082 @default.
• W2092366734 cites W2055972004 @default.
• W2092366734 cites W2056692569 @default.
• W2092366734 cites W2058319426 @default.
• W2092366734 cites W2067160986 @default.
• W2092366734 cites W2077500405 @default.
• W2092366734 cites W2077739282 @default.
• W2092366734 cites W2092453091 @default.
• W2092366734 cites W2093553051 @default.
• W2092366734 cites W2111280484 @default.
• W2092366734 cites W2132639433 @default.
• W2092366734 cites W2138243727 @default.
• W2092366734 cites W2176847391 @default.
• W2092366734 cites W2949357325 @default.
• W2092366734 cites W2950128860 @default.
• W2092366734 cites W2950776376 @default.
• W2092366734 cites W2951666587 @default.
• W2092366734 cites W2951778651 @default.
• W2092366734 cites W2952938431 @default.
• W2092366734 doi "https://doi.org/10.1002/chir.20632" @default.
• W2092366734 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18698641" @default.
• W2092366734 hasPublicationYear "2008" @default.
• W2092366734 type Work @default.
• W2092366734 sameAs 2092366734 @default.
• W2092366734 citedByCount "14" @default.
• W2092366734 countsByYear W20923667342012 @default.
• W2092366734 countsByYear W20923667342015 @default.
• W2092366734 countsByYear W20923667342018 @default.
• W2092366734 countsByYear W20923667342020 @default.
• W2092366734 countsByYear W20923667342022 @default.
• W2092366734 crossrefType "journal-article" @default.
• W2092366734 hasAuthorship W2092366734A5036867911 @default.
• W2092366734 hasAuthorship W2092366734A5059666829 @default.
• W2092366734 hasAuthorship W2092366734A5064837553 @default.
• W2092366734 hasConcept C121332964 @default.
• W2092366734 hasConcept C124668440 @default.
• W2092366734 hasConcept C134121241 @default.
• W2092366734 hasConcept C146686406 @default.
• W2092366734 hasConcept C161790260 @default.
• W2092366734 hasConcept C178790620 @default.
• W2092366734 hasConcept C185592680 @default.
• W2092366734 hasConcept C191897082 @default.
• W2092366734 hasConcept C192562407 @default.
• W2092366734 hasConcept C20621625 @default.
• W2092366734 hasConcept C2776353806 @default.
• W2092366734 hasConcept C2776568683 @default.
• W2092366734 hasConcept C2779815552 @default.
• W2092366734 hasConcept C2780563676 @default.
• W2092366734 hasConcept C2781324293 @default.
• W2092366734 hasConcept C2994363474 @default.
• W2092366734 hasConcept C31903555 @default.
• W2092366734 hasConcept C515207424 @default.
• W2092366734 hasConcept C518881349 @default.
• W2092366734 hasConcept C52703039 @default.
• W2092366734 hasConcept C55493867 @default.
• W2092366734 hasConcept C62520636 @default.
• W2092366734 hasConcept C71240020 @default.
• W2092366734 hasConcept C7602139 @default.
• W2092366734 hasConceptScore W2092366734C121332964 @default.
• W2092366734 hasConceptScore W2092366734C124668440 @default.
• W2092366734 hasConceptScore W2092366734C134121241 @default.
• W2092366734 hasConceptScore W2092366734C146686406 @default.
• W2092366734 hasConceptScore W2092366734C161790260 @default.
• W2092366734 hasConceptScore W2092366734C178790620 @default.
• W2092366734 hasConceptScore W2092366734C185592680 @default.
• W2092366734 hasConceptScore W2092366734C191897082 @default.
• W2092366734 hasConceptScore W2092366734C192562407 @default.
• W2092366734 hasConceptScore W2092366734C20621625 @default.
• W2092366734 hasConceptScore W2092366734C2776353806 @default.
• W2092366734 hasConceptScore W2092366734C2776568683 @default.
• W2092366734 hasConceptScore W2092366734C2779815552 @default.
• W2092366734 hasConceptScore W2092366734C2780563676 @default.
• W2092366734 hasConceptScore W2092366734C2781324293 @default.
• W2092366734 hasConceptScore W2092366734C2994363474 @default.
• W2092366734 hasConceptScore W2092366734C31903555 @default.
• W2092366734 hasConceptScore W2092366734C515207424 @default.
• W2092366734 hasConceptScore W2092366734C518881349 @default.
• W2092366734 hasConceptScore W2092366734C52703039 @default.

• next