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- W2092415568 abstract "Prior to this study several methods for the preparation of C-2 methylene glycosides had been reported. These include Ferrier reaction using BF3×Et2O or InCl3 as well as similar strategies using Nafion-H, Montmorillonite K-10, and Pd(PPh3)4. The present paper utilizes the propargyloxy group as a leaving group in the presence of catalytic AuCl3 to effect SN2′ addition of various functionalized aglycones to propargyloxymethyl glycals. C-2 Methylene glycosides are obtained in moderate yields with stereoselective formation of the α-glycoside." @default.
- W2092415568 created "2016-06-24" @default.
- W2092415568 date "2008-02-21" @default.
- W2092415568 modified "2023-10-18" @default.
- W2092415568 title "Synthesis of C-2 Methylene Glycosides by AuCl3 Catalysis" @default.
- W2092415568 doi "https://doi.org/10.1055/s-2008-1042680" @default.
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