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- W2092451710 abstract "Colloidal particles that are dissolved in a liquid can become charged by preferential adsorption or dissociation of surface molecules. The assumption of a constant surface charge density leads to a particle charge that is proportional to the square of the radius. Recent experiments however have shown that in a number of cases the charge is linearly proportional to its size. We present a simple model for the charging of colloidal particles leading to a linear relation between charge and size in the framework of the mean-field Poisson-Boltzmann theory. The model is based on preferential adsorption or dissociation of surface molecules, in combination with a large concentration of chargeable surface sites. The model also predicts a surface potential that is independent of the particle size. Numerical simulations show that this model is in good agreement with analytical approximations." @default.
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- W2092451710 date "2007-03-30" @default.
- W2092451710 modified "2023-10-01" @default.
- W2092451710 title "Charging mechanism in colloidal particles leading to a linear relation between charge and size" @default.
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- W2092451710 doi "https://doi.org/10.1103/physreve.75.031405" @default.
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