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- W2092473914 abstract "Abstract Complex studies of the intramolecular versus intermolecular hydrogen bond equilibrium and internal rotation of the N,N ‐diethylamine group in 2‐hydroxy‐ N,N ‐diethylbenzamide were conducted. The intramolecular versus intermolecular process in 2‐hydroxy‐ N,N ‐diethylbenzamide was studied by UV–Vis, NMR, IR and Vapour Pressure Osmometric (VPO) methods as a function of temperature and concentration in non‐polar, basic and protic solvents. The unequal positions of the ethyl groups were analysed and the energy barrier to the re‐orientation was defined by the NMR method. This paper presents a study into a complicated nature of competitive interaction 2‐hydroxy‐ N,N ‐diethylbenzamide with the environment by means of the aforesaid methods. Copyright © 2008 John Wiley & Sons, Ltd." @default.
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- W2092473914 date "2008-08-28" @default.
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- W2092473914 title "Intra- versus intermolecular hydrogen bonding equilibrium in 2-hydroxy-<i>N,N</i>-diethylbenzamide" @default.
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- W2092473914 doi "https://doi.org/10.1002/poc.1437" @default.
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