Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092505016> ?p ?o ?g. }
- W2092505016 endingPage "431" @default.
- W2092505016 startingPage "431" @default.
- W2092505016 abstract "In the course of studies on the tandem hydroformylation–reductive amination (hydroaminomethylation), fluorinated mono-phosphines were found to be more active than their more electron-donating counterparts in the enamine hydrogenation step of the reaction; this is in contrast to the widely held view that alkene hydrogenation activity increases with ligand donor strength. DFT calculations comparing the reaction pathways for a simple alkene and a representative enamine show that the rate-determining step changes from the first insertion into a Rh–H bond for but-2-ene to the final reductive elimination step from the Rh–hydride–alkyl species in the enamine hydrogenations." @default.
- W2092505016 created "2016-06-24" @default.
- W2092505016 creator A5015305457 @default.
- W2092505016 creator A5024031026 @default.
- W2092505016 creator A5041480314 @default.
- W2092505016 creator A5049197216 @default.
- W2092505016 creator A5082601608 @default.
- W2092505016 date "2011-01-01" @default.
- W2092505016 modified "2023-10-06" @default.
- W2092505016 title "On the rate-determining step and the ligand electronic effects in rhodium catalysed hydrogenation of enamines and the hydroaminomethylation of alkenes" @default.
- W2092505016 cites W1822538493 @default.
- W2092505016 cites W1983650279 @default.
- W2092505016 cites W1985915812 @default.
- W2092505016 cites W1986119651 @default.
- W2092505016 cites W1992482809 @default.
- W2092505016 cites W1997773128 @default.
- W2092505016 cites W2001470103 @default.
- W2092505016 cites W2001794100 @default.
- W2092505016 cites W2003294522 @default.
- W2092505016 cites W2005126899 @default.
- W2092505016 cites W2010253093 @default.
- W2092505016 cites W2010550597 @default.
- W2092505016 cites W2011330047 @default.
- W2092505016 cites W2026766028 @default.
- W2092505016 cites W2026829714 @default.
- W2092505016 cites W2038836357 @default.
- W2092505016 cites W2040249129 @default.
- W2092505016 cites W2050221163 @default.
- W2092505016 cites W2051543432 @default.
- W2092505016 cites W2052931824 @default.
- W2092505016 cites W2058173090 @default.
- W2092505016 cites W2061836626 @default.
- W2092505016 cites W2072254787 @default.
- W2092505016 cites W2078647562 @default.
- W2092505016 cites W2083346073 @default.
- W2092505016 cites W2086461127 @default.
- W2092505016 cites W2086499294 @default.
- W2092505016 cites W2088085604 @default.
- W2092505016 cites W2092513079 @default.
- W2092505016 cites W2111975642 @default.
- W2092505016 cites W2112393465 @default.
- W2092505016 cites W2122321303 @default.
- W2092505016 cites W2128964443 @default.
- W2092505016 cites W2130281103 @default.
- W2092505016 cites W2133503655 @default.
- W2092505016 cites W2137360541 @default.
- W2092505016 cites W2139083301 @default.
- W2092505016 cites W2142636122 @default.
- W2092505016 cites W2144148042 @default.
- W2092505016 cites W2152176028 @default.
- W2092505016 cites W2160382712 @default.
- W2092505016 cites W2317044837 @default.
- W2092505016 cites W2950895984 @default.
- W2092505016 cites W2951047657 @default.
- W2092505016 cites W2951272483 @default.
- W2092505016 cites W2952098964 @default.
- W2092505016 cites W2952264934 @default.
- W2092505016 cites W2952735374 @default.
- W2092505016 cites W2953116940 @default.
- W2092505016 cites W4235285677 @default.
- W2092505016 doi "https://doi.org/10.1039/c1cy00026h" @default.
- W2092505016 hasPublicationYear "2011" @default.
- W2092505016 type Work @default.
- W2092505016 sameAs 2092505016 @default.
- W2092505016 citedByCount "34" @default.
- W2092505016 countsByYear W20925050162012 @default.
- W2092505016 countsByYear W20925050162013 @default.
- W2092505016 countsByYear W20925050162014 @default.
- W2092505016 countsByYear W20925050162015 @default.
- W2092505016 countsByYear W20925050162016 @default.
- W2092505016 countsByYear W20925050162018 @default.
- W2092505016 countsByYear W20925050162019 @default.
- W2092505016 countsByYear W20925050162020 @default.
- W2092505016 countsByYear W20925050162021 @default.
- W2092505016 countsByYear W20925050162022 @default.
- W2092505016 countsByYear W20925050162023 @default.
- W2092505016 crossrefType "journal-article" @default.
- W2092505016 hasAuthorship W2092505016A5015305457 @default.
- W2092505016 hasAuthorship W2092505016A5024031026 @default.
- W2092505016 hasAuthorship W2092505016A5041480314 @default.
- W2092505016 hasAuthorship W2092505016A5049197216 @default.
- W2092505016 hasAuthorship W2092505016A5082601608 @default.
- W2092505016 hasConcept C116569031 @default.
- W2092505016 hasConcept C155647269 @default.
- W2092505016 hasConcept C161790260 @default.
- W2092505016 hasConcept C170493617 @default.
- W2092505016 hasConcept C178790620 @default.
- W2092505016 hasConcept C185592680 @default.
- W2092505016 hasConcept C21951064 @default.
- W2092505016 hasConcept C521398313 @default.
- W2092505016 hasConcept C55493867 @default.
- W2092505016 hasConceptScore W2092505016C116569031 @default.
- W2092505016 hasConceptScore W2092505016C155647269 @default.
- W2092505016 hasConceptScore W2092505016C161790260 @default.
- W2092505016 hasConceptScore W2092505016C170493617 @default.
- W2092505016 hasConceptScore W2092505016C178790620 @default.
- W2092505016 hasConceptScore W2092505016C185592680 @default.
- W2092505016 hasConceptScore W2092505016C21951064 @default.