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- W2092557327 endingPage "1190" @default.
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- W2092557327 abstract "The 2,6-py(CH2-pz)2 ligand was used to prepare metal complexes as follows: [py(CH2pz)2](BiI3), {Ag[py(CH2pz)2](OTf)·CH3CN}∞, {PtCl[py(CH2pz)2]}(BF4), {Cd[py(CH2pz)2]2}(BF4)2·[4,4‘-bipy]·0.5H2O, and {Cd[phen]3}2(BF4)4·[py(CH2pz)2]·5H2O (py = pyridyl, pz = pyrazolyl, and phen = 1,10-phenanthroline). The solid state structures of each complex show that all five compounds are organized by noncovalent forces into complex extended structures. Each structure has a common supramolecular organizational feature between the ligands of a cooperative offset face-to-face π−π stacking and C−H···π interaction formed from both the pyridyl and the pyrazolyl rings that is termed the aryl−pyrazolyl embrace. The systematic analysis of this synthon showed that the π−π stacking component of the aryl−pyrazolyl embrace always involves rings of the same type." @default.
- W2092557327 created "2016-06-24" @default.
- W2092557327 creator A5027404750 @default.
- W2092557327 creator A5034938361 @default.
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- W2092557327 date "2005-02-17" @default.
- W2092557327 modified "2023-10-18" @default.
- W2092557327 title "Metal Complexes of 2,6-Bis[(pyrazol-1-yl)methyl]pyridine: The Search for Aryl−Pyrazolyl Embrace Interactions as a Synthon for Crystal Engineering" @default.
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- W2092557327 doi "https://doi.org/10.1021/cg049609s" @default.
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