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- W2092559050 abstract "Abstract Catalytic hydrogenation that utilizes frustrated Lewis pair (FLP) catalysts is a subject of growing interest because such catalysts offer a unique opportunity for the development of transition‐metal‐free hydrogenations. The aim of our recent efforts is to further increase the functional‐group tolerance and chemoselectivity of FLP catalysts by means of size‐exclusion catalyst design. Given that hydrogen molecule is the smallest molecule, our modified Lewis acids feature a highly shielded boron center that still allows the cleavage of the hydrogen but avoids undesirable FLP reactivity by simple physical constraint. As a result, greater latitude in substrate scope can be achieved, as exemplified by the chemoselective reduction of α,β‐unsaturated imines, ketones, and quinolines. In addition to synthetic aspects, detailed NMR spectroscopic, DFT, and 2 H isotopic labeling studies were performed to gain further mechanistic insight into FLP hydrogenation." @default.
- W2092559050 created "2016-06-24" @default.
- W2092559050 creator A5027176622 @default.
- W2092559050 creator A5046032148 @default.
- W2092559050 creator A5048846178 @default.
- W2092559050 creator A5055602019 @default.
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- W2092559050 creator A5064012236 @default.
- W2092559050 creator A5072056266 @default.
- W2092559050 creator A5088625711 @default.
- W2092559050 date "2011-12-12" @default.
- W2092559050 modified "2023-10-18" @default.
- W2092559050 title "Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids" @default.
- W2092559050 cites W1536161922 @default.
- W2092559050 cites W1964276731 @default.
- W2092559050 cites W1964740687 @default.
- W2092559050 cites W1969321380 @default.
- W2092559050 cites W1977909846 @default.
- W2092559050 cites W1977918492 @default.
- W2092559050 cites W1980543768 @default.
- W2092559050 cites W1981600895 @default.
- W2092559050 cites W1982406806 @default.
- W2092559050 cites W1982907022 @default.
- W2092559050 cites W1983806218 @default.
- W2092559050 cites W1984018926 @default.
- W2092559050 cites W1984083274 @default.
- W2092559050 cites W1985065274 @default.
- W2092559050 cites W1986228477 @default.
- W2092559050 cites W1986432139 @default.
- W2092559050 cites W1986695985 @default.
- W2092559050 cites W1993967079 @default.
- W2092559050 cites W1994567008 @default.
- W2092559050 cites W1995053726 @default.
- W2092559050 cites W1997683728 @default.
- W2092559050 cites W2000412424 @default.
- W2092559050 cites W2006577807 @default.
- W2092559050 cites W2006898622 @default.
- W2092559050 cites W2008691057 @default.
- W2092559050 cites W2009797574 @default.
- W2092559050 cites W2013668323 @default.
- W2092559050 cites W2013877033 @default.
- W2092559050 cites W2016913594 @default.
- W2092559050 cites W2018923471 @default.
- W2092559050 cites W2020388883 @default.
- W2092559050 cites W2020891256 @default.
- W2092559050 cites W2021427508 @default.
- W2092559050 cites W2022619038 @default.
- W2092559050 cites W2032618872 @default.
- W2092559050 cites W2033559834 @default.
- W2092559050 cites W2033688675 @default.
- W2092559050 cites W2037577788 @default.
- W2092559050 cites W2037935642 @default.
- W2092559050 cites W2039396938 @default.
- W2092559050 cites W2041836626 @default.
- W2092559050 cites W2042739813 @default.
- W2092559050 cites W2043680511 @default.
- W2092559050 cites W2045914232 @default.
- W2092559050 cites W2048390203 @default.
- W2092559050 cites W2051085799 @default.
- W2092559050 cites W2053157033 @default.
- W2092559050 cites W2057344624 @default.
- W2092559050 cites W2059131789 @default.
- W2092559050 cites W2061936071 @default.
- W2092559050 cites W2063772997 @default.
- W2092559050 cites W2067850694 @default.
- W2092559050 cites W2068039664 @default.
- W2092559050 cites W2068294205 @default.
- W2092559050 cites W2068823643 @default.
- W2092559050 cites W2069890553 @default.
- W2092559050 cites W2071033467 @default.
- W2092559050 cites W2075903690 @default.
- W2092559050 cites W2076878961 @default.
- W2092559050 cites W2080049571 @default.
- W2092559050 cites W2084249815 @default.
- W2092559050 cites W2088064072 @default.
- W2092559050 cites W2091521120 @default.
- W2092559050 cites W2094249848 @default.
- W2092559050 cites W2094635504 @default.
- W2092559050 cites W2106634665 @default.
- W2092559050 cites W2107559437 @default.
- W2092559050 cites W2109746413 @default.
- W2092559050 cites W2110128916 @default.
- W2092559050 cites W2115378983 @default.
- W2092559050 cites W2115786060 @default.
- W2092559050 cites W2118180102 @default.
- W2092559050 cites W2118787075 @default.
- W2092559050 cites W2120749361 @default.
- W2092559050 cites W2121455509 @default.
- W2092559050 cites W2121686700 @default.
- W2092559050 cites W2128643931 @default.
- W2092559050 cites W2135819883 @default.
- W2092559050 cites W2136252185 @default.
- W2092559050 cites W2138227189 @default.
- W2092559050 cites W2138465265 @default.
- W2092559050 cites W2141698905 @default.
- W2092559050 cites W2143453620 @default.
- W2092559050 cites W2162680777 @default.
- W2092559050 cites W2166870100 @default.