FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092562479> ?p ?o ?g. }

• W2092562479 endingPage "1188" @default.
• W2092562479 startingPage "1177" @default.
• W2092562479 abstract "Diphenyl ditelluride (phTeTePh) adds to a variety of acetylenes upon irradiation with visible light in the absence of solvent to provide vic-bis(phenyltelluro)alkenes in good yields. The reaction may proceed by a radical-chain mechanism that includes the addition to acetylenes of phenyltelluro radical (PhTee) generated in situ by photolysis of diphenyl ditelluride, followed by the SH2 reaction between thus formed β-(phenyltelluro)alkenyl radicals and diphenyl ditelluride. In the cases of unactivated acetylenes such as 1-octyne, the addition proceeds stereoselectively to provide only (E)-vic-bis(phenyltelluro)alkenes. Contrary to this, activated acetylenes like phenylacetylene give rise to a mixture of E- and Z-isomers of vic-bis(phenyltelluro)alkenes. Since the obtained vic-bis(phenyltelluro)alkenes indicate absorption in the near-UV, irradiation with near-UV light in solvent causes a novel reverse reaction of the adducts to the starting acetylenes and diphenyl ditelluride. Accordingly, irradiation with visible light (>400 nm) under high concentrations of the substrates induces the addition of (PhTe)2 to acetylenes, whereas irradiation with near-ultraviolet (>300 nm) under dilution condition causes the reverse reaction." @default.
• W2092562479 created "2016-06-24" @default.
• W2092562479 creator A5021615738 @default.
• W2092562479 creator A5029057166 @default.
• W2092562479 creator A5030550862 @default.
• W2092562479 creator A5036244962 @default.
• W2092562479 creator A5045209143 @default.
• W2092562479 creator A5078826041 @default.
• W2092562479 date "1993-02-01" @default.
• W2092562479 modified "2023-10-12" @default.
• W2092562479 title "Photo-Induced Ditelluration of Acetylenes with Diphenyl Ditelluride" @default.
• W2092562479 cites W1966460750 @default.
• W2092562479 cites W1974103639 @default.
• W2092562479 cites W1974567216 @default.
• W2092562479 cites W1980002499 @default.
• W2092562479 cites W1980798248 @default.
• W2092562479 cites W2005351626 @default.
• W2092562479 cites W2009949000 @default.
• W2092562479 cites W2025263520 @default.
• W2092562479 cites W2027233543 @default.
• W2092562479 cites W2030320221 @default.
• W2092562479 cites W2050626106 @default.
• W2092562479 cites W2052487615 @default.
• W2092562479 cites W2063855139 @default.
• W2092562479 cites W2066587009 @default.
• W2092562479 cites W2076370931 @default.
• W2092562479 cites W2093511747 @default.
• W2092562479 cites W2099839666 @default.
• W2092562479 cites W2140611387 @default.
• W2092562479 cites W2148984919 @default.
• W2092562479 cites W2167181505 @default.
• W2092562479 cites W2313319017 @default.
• W2092562479 cites W2338778863 @default.
• W2092562479 cites W2396357902 @default.
• W2092562479 cites W2949314142 @default.
• W2092562479 cites W2949554593 @default.
• W2092562479 cites W2949639077 @default.
• W2092562479 cites W2949675778 @default.
• W2092562479 cites W2951339737 @default.
• W2092562479 cites W3004852279 @default.
• W2092562479 cites W3024909882 @default.
• W2092562479 cites W3197999579 @default.
• W2092562479 doi "https://doi.org/10.1016/s0040-4020(01)85809-9" @default.
• W2092562479 hasPublicationYear "1993" @default.
• W2092562479 type Work @default.
• W2092562479 sameAs 2092562479 @default.
• W2092562479 citedByCount "66" @default.
• W2092562479 countsByYear W20925624792012 @default.
• W2092562479 countsByYear W20925624792013 @default.
• W2092562479 countsByYear W20925624792014 @default.
• W2092562479 countsByYear W20925624792016 @default.
• W2092562479 countsByYear W20925624792017 @default.
• W2092562479 countsByYear W20925624792020 @default.
• W2092562479 countsByYear W20925624792021 @default.
• W2092562479 countsByYear W20925624792022 @default.
• W2092562479 countsByYear W20925624792023 @default.
• W2092562479 crossrefType "journal-article" @default.
• W2092562479 hasAuthorship W2092562479A5021615738 @default.
• W2092562479 hasAuthorship W2092562479A5029057166 @default.
• W2092562479 hasAuthorship W2092562479A5030550862 @default.
• W2092562479 hasAuthorship W2092562479A5036244962 @default.
• W2092562479 hasAuthorship W2092562479A5045209143 @default.
• W2092562479 hasAuthorship W2092562479A5078826041 @default.
• W2092562479 hasConcept C104663316 @default.
• W2092562479 hasConcept C108204754 @default.
• W2092562479 hasConcept C111337013 @default.
• W2092562479 hasConcept C121332964 @default.
• W2092562479 hasConcept C139066938 @default.
• W2092562479 hasConcept C155647269 @default.
• W2092562479 hasConcept C161790260 @default.
• W2092562479 hasConcept C178790620 @default.
• W2092562479 hasConcept C185544564 @default.
• W2092562479 hasConcept C185592680 @default.
• W2092562479 hasConcept C2778545935 @default.
• W2092562479 hasConcept C2780471494 @default.
• W2092562479 hasConcept C49040817 @default.
• W2092562479 hasConcept C54582936 @default.
• W2092562479 hasConcept C75473681 @default.
• W2092562479 hasConceptScore W2092562479C104663316 @default.
• W2092562479 hasConceptScore W2092562479C108204754 @default.
• W2092562479 hasConceptScore W2092562479C111337013 @default.
• W2092562479 hasConceptScore W2092562479C121332964 @default.
• W2092562479 hasConceptScore W2092562479C139066938 @default.
• W2092562479 hasConceptScore W2092562479C155647269 @default.
• W2092562479 hasConceptScore W2092562479C161790260 @default.
• W2092562479 hasConceptScore W2092562479C178790620 @default.
• W2092562479 hasConceptScore W2092562479C185544564 @default.
• W2092562479 hasConceptScore W2092562479C185592680 @default.
• W2092562479 hasConceptScore W2092562479C2778545935 @default.
• W2092562479 hasConceptScore W2092562479C2780471494 @default.
• W2092562479 hasConceptScore W2092562479C49040817 @default.
• W2092562479 hasConceptScore W2092562479C54582936 @default.
• W2092562479 hasConceptScore W2092562479C75473681 @default.
• W2092562479 hasIssue "6" @default.
• W2092562479 hasLocation W20925624791 @default.
• W2092562479 hasOpenAccess W2092562479 @default.
• W2092562479 hasPrimaryLocation W20925624791 @default.
• W2092562479 hasRelatedWork W1969486662 @default.

• next