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- W2092565892 abstract "The synthesis of a 15-membered macrocyclic triene containing all the required substituents of ring A of (+)-aphidicolin (1) is reported. This compound underwent a thermal transannular cycloaddition followed by an intramolecular aldol reaction to yield tetracycle 32 containing 8 chiral centers which is considered a key intermediate for the synthesis of (+)-aphidicolin and related analogs." @default.
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- W2092565892 date "2003-04-01" @default.
- W2092565892 modified "2023-10-18" @default.
- W2092565892 title "New approach toward the total synthesis of (+)-aphidicolin by tandem transannular Diels–Alder/aldol strategy" @default.
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- W2092565892 doi "https://doi.org/10.1016/s0040-4020(03)00372-7" @default.
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