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- W2092566583 abstract "Abstract The reaction of RhCl3 with 1-alkyl-2-(naphthyl-α-azo)imidazole (α-NaiR, N, N′chelator) (R = CH3, CH2–CH3, CH2–Ph) has synthesized a coordination compound, [Rh(α-NaiR-N, N′)(PPh3)Cl3] (2) from boiling methanol in the presence of PPh3 while the reaction under similar condition in the presence of Et3N has synthesized cyclometallated complex, [Rh(α-NaiR-N, N′, C)(PPh3)Cl2] (3). The structures of both types of complexes are confirmed by single crystal X-ray diffraction study in representative cases. All the complexes have been characterized by spectral data (FT-IR, UV–VIS, MS, 1H-NMR) and elemental analyses. Density functional theory calculation has also been performed to rationalize the electronic structures and their spectral properties." @default.
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- W2092566583 date "2013-05-01" @default.
- W2092566583 modified "2023-09-26" @default.
- W2092566583 title "The C–H activation of pendant naphthyl group of 1-alkyl-2-(naphthyl-α-azo)imidazole by rhodium(III). Spectral, structural characterization and, DFT computation" @default.
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- W2092566583 doi "https://doi.org/10.1016/j.jorganchem.2013.02.013" @default.
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