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- W2092567448 abstract "An organic molecule containing cobalt phosphate (denoted CoPO-GIS) which is isostructural with the zeolite gismondine has been synthesized under solvothermal conditions by using [Co(en)3]Cl3 and phosphoric acid as the reactants and ethylene glycol as the solvent. CoPO-GIS ((H3NCH2CH2NH3)0.5.CoPO4) crystallizes in the monoclinic space group C2/c with a = 14.744(3) A, b = 8.850(3) A, c = 10.062(3) A, beta = 131.609(19) degrees, and Z = 8. The structure consists of a 3-D network of strictly alternating CoO4 and PO4 tetrahedra interconnected by oxygen bridges, and the charge-balancing diprotonated ethylenediamine cations are highly ordered in the cages of the CoPO4 framework. CoPO-GIS is the only amine-containing cobalt phosphate with a known zeolite topology." @default.
- W2092567448 created "2016-06-24" @default.
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- W2092567448 date "2000-03-16" @default.
- W2092567448 modified "2023-10-14" @default.
- W2092567448 title "The First Organo-Templated Cobalt Phosphate with a Zeolite Topology" @default.
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- W2092567448 doi "https://doi.org/10.1021/ic990719b" @default.
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