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- W2092576264 abstract "This calculation demonstrates that the combined configuration-interaction-Hylleraas (CI-Hy) variational method of Sims and Hagstrom can be applied to the $^{1}S$ ground state of the neon atom. Coordinates ${r}_{mathrm{ij}}$ have been included in the wave function so as to correlate explicitly the motion of all pairs of electrons in the atom. An energy of - 128.8298 hartree has been obtained from an 83-term wave function (73.5% of the correlation energy). An analysis of the pair correlation energies shows that it is more difficult to represent the electronic correlation in $p$-$p$ and $s$-$p$ pairs than $s$-$s$ pairs using Hylleraas functions. More experience with CI-Hy calculations on atoms containing as many as ten electrons is required before the method can compete with and give higher accuracy than the conventional CI calculations." @default.
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- W2092576264 title "CI-Hylleraas variational calculation on the ground state of the neon atom" @default.
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- W2092576264 doi "https://doi.org/10.1103/physreva.14.1607" @default.
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