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• W2092578953 abstract "The first unambiguous identification of a finite rumpling of the ions in the (100) face of a rocksalt-structure compound has been made by means of an extension of a previous LEED theory/experiment comparison for MgO (100) carried out using a new and extensive I(V) data set recorded over the energy range between 20 and 150 eV. These data were obtained from an air-cleaved sample using a novel, computer-controlled spectrum acquisition system, surface charging effects being eliminated by application of a primary energy modulation technique. An R-factor analysis was used to locate the optimum structural solution. This involves a differential relaxation of the top layer ions of 0.04 AA with an associated mean surface relaxation of zero, a result which agrees well with the most recent shell model calculations. This finding is discussed in relation to the postulated existence of a structural phase transition at the MgO (100) surface and its implications for the type of chemical bonding operative in the region are assessed." @default.
• W2092578953 created "2016-06-24" @default.
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• W2092578953 date "1982-09-30" @default.
• W2092578953 modified "2023-10-16" @default.
• W2092578953 title "A LEED study of the MgO (100) surface: identification of a finite rumple" @default.
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• W2092578953 doi "https://doi.org/10.1088/0022-3719/15/27/024" @default.
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