FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092582908> ?p ?o ?g. }

• W2092582908 endingPage "547" @default.
• W2092582908 startingPage "539" @default.
• W2092582908 abstract "Abstract Summary: Non‐isothermal crystallization behavior of PTT resins synthesized with different catalysts was studied by using differential scanning calorimetry (DSC) and polarized light microscopy (PLM). The results showed that with the increase of the cooling rate, the crystallization temperature for poly(trimethylene terephthalate) (PTT) resin decreased, which indicated that the crystallization process was controlled by the nucleation. Catalyst had no effect on the crystallization development process, but had somewhat effect on the non‐isothermal crystallization mechanism. The average values of Avrami exponent, for PTT with different catalysts were between 3 and 4. It was assumed that the non‐isothermal crystallization mechanism for PTT with or without catalyst was the combination of homogenous and heterogeneous nucleation and spherulite growth, but it mainly depended on the latter. For sample 4, the non‐isothermal crystallization underwent secondary crystallization process when cooling rate was over 20 °C/min. At the same cooling rate, the crystallization temperature, the crystallization ability and the crystallization rate of PTT resins followed the sequence as: sample 2 > sample 1 ≈ sample 3 ≈ sample 4, which proved that catalysts could significantly prompt crystallization. The cooling rate had significant effect on the crystallization ability parameters of PTT, i.e., with the increase of cooling rate, the crystallization ability declined. Although catalyst could increase the crystallization ability of PTT, the effect was very limited because the effect of the molecular weight on the crystallization ability would be superior to the catalyst when the molecular weight of PTT was significantly high. The specific surface area of catalyst had also a great influence on the spherulitic morphology of PTT formed in the cooling process. The spherulite dimensions decrease with increasing the specific surface area of catalyst because of an increase in the nucleation rate, which produces more and smaller spherulites that can not grow larger before impinging on each other. magnified image" @default.
• W2092582908 created "2016-06-24" @default.
• W2092582908 creator A5024109962 @default.
• W2092582908 creator A5029030051 @default.
• W2092582908 creator A5042524338 @default.
• W2092582908 creator A5067570437 @default.
• W2092582908 creator A5088529372 @default.
• W2092582908 date "2004-06-15" @default.
• W2092582908 modified "2023-10-09" @default.
• W2092582908 title "Non-Isothermal Crystallization Behavior of Poly(trimethylene terephthalate) Synthesized with Different Catalysts" @default.
• W2092582908 cites W1584379345 @default.
• W2092582908 cites W1964508281 @default.
• W2092582908 cites W1964740351 @default.
• W2092582908 cites W1965948651 @default.
• W2092582908 cites W1970920455 @default.
• W2092582908 cites W1973607352 @default.
• W2092582908 cites W1978195940 @default.
• W2092582908 cites W1995202423 @default.
• W2092582908 cites W2015861351 @default.
• W2092582908 cites W2017941616 @default.
• W2092582908 cites W2025809669 @default.
• W2092582908 cites W2031293319 @default.
• W2092582908 cites W2031682144 @default.
• W2092582908 cites W2038700345 @default.
• W2092582908 cites W2041285410 @default.
• W2092582908 cites W2054463121 @default.
• W2092582908 cites W2075274202 @default.
• W2092582908 cites W2080144732 @default.
• W2092582908 cites W2127990915 @default.
• W2092582908 doi "https://doi.org/10.1002/mame.200300305" @default.
• W2092582908 hasPublicationYear "2004" @default.
• W2092582908 type Work @default.
• W2092582908 sameAs 2092582908 @default.
• W2092582908 citedByCount "17" @default.
• W2092582908 countsByYear W20925829082012 @default.
• W2092582908 countsByYear W20925829082013 @default.
• W2092582908 countsByYear W20925829082015 @default.
• W2092582908 countsByYear W20925829082022 @default.
• W2092582908 crossrefType "journal-article" @default.
• W2092582908 hasAuthorship W2092582908A5024109962 @default.
• W2092582908 hasAuthorship W2092582908A5029030051 @default.
• W2092582908 hasAuthorship W2092582908A5042524338 @default.
• W2092582908 hasAuthorship W2092582908A5067570437 @default.
• W2092582908 hasAuthorship W2092582908A5088529372 @default.
• W2092582908 hasConcept C121332964 @default.
• W2092582908 hasConcept C127413603 @default.
• W2092582908 hasConcept C133347239 @default.
• W2092582908 hasConcept C161790260 @default.
• W2092582908 hasConcept C178790620 @default.
• W2092582908 hasConcept C185592680 @default.
• W2092582908 hasConcept C188027245 @default.
• W2092582908 hasConcept C192562407 @default.
• W2092582908 hasConcept C203036418 @default.
• W2092582908 hasConcept C39519442 @default.
• W2092582908 hasConcept C42360764 @default.
• W2092582908 hasConcept C5556706 @default.
• W2092582908 hasConcept C61048295 @default.
• W2092582908 hasConcept C97355855 @default.
• W2092582908 hasConceptScore W2092582908C121332964 @default.
• W2092582908 hasConceptScore W2092582908C127413603 @default.
• W2092582908 hasConceptScore W2092582908C133347239 @default.
• W2092582908 hasConceptScore W2092582908C161790260 @default.
• W2092582908 hasConceptScore W2092582908C178790620 @default.
• W2092582908 hasConceptScore W2092582908C185592680 @default.
• W2092582908 hasConceptScore W2092582908C188027245 @default.
• W2092582908 hasConceptScore W2092582908C192562407 @default.
• W2092582908 hasConceptScore W2092582908C203036418 @default.
• W2092582908 hasConceptScore W2092582908C39519442 @default.
• W2092582908 hasConceptScore W2092582908C42360764 @default.
• W2092582908 hasConceptScore W2092582908C5556706 @default.
• W2092582908 hasConceptScore W2092582908C61048295 @default.
• W2092582908 hasConceptScore W2092582908C97355855 @default.
• W2092582908 hasIssue "6" @default.
• W2092582908 hasLocation W20925829081 @default.
• W2092582908 hasOpenAccess W2092582908 @default.
• W2092582908 hasPrimaryLocation W20925829081 @default.
• W2092582908 hasRelatedWork W1559947375 @default.
• W2092582908 hasRelatedWork W1972120195 @default.
• W2092582908 hasRelatedWork W1989977061 @default.
• W2092582908 hasRelatedWork W1993708726 @default.
• W2092582908 hasRelatedWork W2030980709 @default.
• W2092582908 hasRelatedWork W2059477440 @default.
• W2092582908 hasRelatedWork W2065212154 @default.
• W2092582908 hasRelatedWork W2068422109 @default.
• W2092582908 hasRelatedWork W2376350756 @default.
• W2092582908 hasRelatedWork W86446358 @default.
• W2092582908 hasVolume "289" @default.
• W2092582908 isParatext "false" @default.
• W2092582908 isRetracted "false" @default.
• W2092582908 magId "2092582908" @default.
• W2092582908 workType "article" @default.