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• W2092600639 abstract "This work reports rhodium–xantphos as a new catalytic system for cyanide-free cyanation of aryl halides to aryl nitriles. The reaction takes place in the presence of phosphorous oxychloride as an acid and formamide as a cyanide source cum solvent. The developed protocol avoids the use of highly toxic metal cyanides. This methodology is a simple, single step reaction involving formamide as a safe and nontoxic source of cyanation. A variety of aryl iodides/bromides were well tolerated under optimized reaction conditions providing moderate to excellent yield of corresponding cyanides." @default.
• W2092600639 created "2016-06-24" @default.
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• W2092600639 date "2013-05-01" @default.
• W2092600639 modified "2023-09-25" @default.
• W2092600639 title "Rhodium catalyzed cyanide-free cyanation of aryl halide by using formamide as a cyanide source" @default.
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• W2092600639 doi "https://doi.org/10.1016/j.tetlet.2013.03.052" @default.
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