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- W2092607367 abstract "Electrochemical oxidation of [Bu4N][Ni(dmise)2] in the presence of Me4NPF6 yields [Me4N][Ni(dmise)2]2, the selenone derivative of the superconducting [Me4N][Ni(dmit)2]2. The X-ray structure of [Me4N][Ni(dmise)2]2 reveals a non-stacking arrangement of paired anions. The [Ni(dmise)2]2 diads are connected along the c-axis via a short intermolecular Se…Se contact of 3.277(3) A. Preliminary conductivity measurements show a room temperature conductivity of 20 S cm−1 with a metallic behavior down to 140 K, at which point a metalinsulator transition occurs." @default.
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- W2092607367 date "2010-08-22" @default.
- W2092607367 modified "2023-09-26" @default.
- W2092607367 title "ChemInform Abstract: Synthesis and Structure of (Me4N)(Ni(dmise)2)2, the First Conductor Based on the Ni(C3S4Se)2 System." @default.
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- W2092607367 doi "https://doi.org/10.1002/chin.199144261" @default.
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