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- W2092607514 abstract "Abstract Compound formation was observed when acidic solutions of uranyl chloride were mixed with cationic alkyl pyridinium chloride surfactants above their critical micellar concentrations. The compounds with dodecyl and hexadecyl pyridinium chlorides (LPC or CPC) were isolated in crystalline form, analysed for elemental composition, and IR and fluorescence spectra recorded. The compounds have a molecular formula S 2 UO 2 Cl 4 , where S is the alkyl pyridinium group. X-ray diffraction showed the (CP) 2 UO 2 Cl 4 crystals to be triclinic. TG, DTA and DSC studies show that (CP) 2 UO 2 Cl 4 melts reversibly at ~395 K and loses ligand at ~ 563 K. The heat of fusion of the compound was found to be 60.94 ±0.33 kJ mol −1 with a corresponding entropy change of 38 eu mol −1 . Thermal decomposition studies in vacuo show that the uranyl ions sensitise the decomposition of the compound (CP) 2 UO 2 Cl 4 . A probable mechanism by which the micellar environment may induce chlorocomplexation of the uranyl ion is discussed." @default.
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- W2092607514 date "1988-08-01" @default.
- W2092607514 modified "2023-09-27" @default.
- W2092607514 title "Thermal and spectral characterisation of compounds of the uranyl ion with surfactants" @default.
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- W2092607514 doi "https://doi.org/10.1016/0040-6031(88)80060-1" @default.
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