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• W2092620032 abstract "The use of NMP (N-methylpyrrolidone) as a cosolvent has been shown to improve the yield of iron-catalyzed cross-coupling reactions, but surprisingly there are no iron complexes of NMP in the literature. This paper reports two novel NMP complexes of iron(II): Fe3Cl6(NMP)8 and LtBuFe(NMP)Cl (LtBu = bulky β-diketiminate ligand). The X-ray crystal structure of Fe3Cl6(NMP)8 shows an octahedral Fe(NMP)62+ cation and two tetrahedral FeCl3(NMP)− anions. 1H NMR spectra show that the NMP ligands are labile, exchanging rapidly on the NMR time scale. The β-diketiminate complex has a trigonal pyramidal geometry with the NMP in an axial position. The use of NMP improves the yield of the catalytic cross-coupling of methyl 4-chlorobenzoate and 1-hexylmagnesium bromide using these and other iron complexes as precatalysts." @default.
• W2092620032 created "2016-06-24" @default.
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• W2092620032 date "2009-12-01" @default.
• W2092620032 modified "2023-09-27" @default.
• W2092620032 title "Coordination of N-methylpyrrolidone to iron(II)" @default.
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• W2092620032 doi "https://doi.org/10.1016/j.jorganchem.2009.09.005" @default.
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