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• W2092626089 endingPage "4885" @default.
• W2092626089 startingPage "4872" @default.
• W2092626089 abstract "Abstract The dinuclear mixed‐valent complex [(MeC 5 H 4 )(dmpe)MnC 2 Mn(dmpe)(C 5 H 4 Me)] + [(η 2 ‐MeC 5 H 4 ) 3 Mn] − [ 1 ] + [ 2 ] − (dmpe=1,2‐bis(dimethylphosphanyl)ethane) was prepared by the reaction of [Mn(MeC 5 H 4 ) 2 ] with dmpe and Me 3 SnCCSnMe 3 . The reactions of [ 1 ] + [ 2 ] − with K[PF 6 ] and Na[BPh 4 ] yielded the corresponding anion metathesis products [(MeC 5 H 4 )(dmpe)MnC 2 Mn(dmpe)(C 5 H 4 Me)][PF 6 ] ([ 1 ][PF 6 ]) and [(MeC 5 H 4 )(dmpe)MnC 2 Mn(dmpe)(C 5 H 4 Me)][BPh 4 ] ([ 1 ][BPh 4 ]). These mixed‐valent species can be reduced to the neutral form by reaction with Na/Hg. The obtained complex [(MeC 5 H 4 )(dmpe)MnC 2 Mn(dmpe)(C 5 H 4 Me)] ( 1 ) displays a triplet/singlet spin equilibrium in solution and in the solid state, which was additionally studied by DFT calculations. The diamagnetic dicationic species [(MeC 5 H 4 )(dmpe)MnC 2 Mn(dmpe)(C 5 H 4 Me)][PF 6 ] 2 ([ 1 ][PF 6 ] 2 ) was obtained by oxidizing the mixed‐valent complex [ 1 ][PF 6 ] with one equivalent of [Fe(C 5 H 5 ) 2 ][PF 6 ]. Both redox processes are fully reversible. The dinuclear compounds were characterized by NMR, IR, UV‐visible, and Raman spectroscopy, cyclic voltammetry, and magnetic susceptibility measurements. X‐ray diffraction studies were performed on [ 1 ][ 2 ], [ 1 ][PF 6 ], [ 1 ][BPh 4 ], and [ 1 ][PF 6 ] 2 ." @default.
• W2092626089 created "2016-06-24" @default.
• W2092626089 creator A5001794559 @default.
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• W2092626089 creator A5047826736 @default.
• W2092626089 date "2004-09-22" @default.
• W2092626089 modified "2023-10-10" @default.
• W2092626089 title "Facile Access to Redox-Active C2-Bridged Complexes with Half-Sandwich Manganese End Groups" @default.
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