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- W2092639478 abstract "Abstract Highly soluble dendritic branches with two, four, eight or 16 methanofullerene subunits at their peripheries and carboxylic acid functions at their focal points have been prepared by a convergent approach. Starting from a methanofullerene derivative possessing a tert ‐butyl ester function, the successive dendrimer generations were obtained by repetition of a reaction sequence involving cleavage of the tert ‐butyl ester moiety under acidic conditions, followed by a DCC‐mediated esterification reaction with an A 2 B building block possessing two benzylic alcohol functions and a tert ‐butyl ester group. This repetitive synthetic sequence is very efficient and allowed the dendritic growth up to the fifth‐generation derivative, containing 16 peripheral fullerene subunits. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2092639478 date "2005-12-14" @default.
- W2092639478 modified "2023-10-16" @default.
- W2092639478 title "Synthesis of Dendritic Branches with Peripheral Fullerene Subunits" @default.
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- W2092639478 doi "https://doi.org/10.1002/ejoc.200500653" @default.
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