FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092691569> ?p ?o ?g. }

• W2092691569 endingPage "118" @default.
• W2092691569 startingPage "113" @default.
• W2092691569 abstract "For blends of styrene−butadiene (SB) diblock copolymers in entangling, high-M homopolybutadiene (hB) matrices, two-step viscoelastic relaxation behavior found in a previous study (Watanabe, H.; Kotaka. T. Macromolecules 1984, 17, 342) was reexamined to elucidate features of the fast process on the basis of recently accumulated knowledge for relaxation of homopolymer blends. The SB/hB blends contained spherical micelles with S cores and B corona. For the fast process, the micelles exhibited nearly universal dependence of reduced moduli, Gr* = [MbB/cbBRT]G*SB, on reduced frequencies, ωτ*, with cbB and MbB being the concentration of the B blocks in the hB matrix and the B block molecular weight, respectively, and τ* being the relaxation time of the fast process. Behavior of τ* changed with MbB, cbB, and the matrix molecular weight MhB. For dilute micelles with cbB < ce (entanglement threshold for the B blocks), the B blocks were entangled only with the hB matrix and τ* were found to be close to constraint release (CR) relaxation times τCR evaluated from data for star-hB blends. This result led us to attribute the fast process of the dilute micelles to CR relaxation of the B blocks due to the matrix motion. On the other hand, for concentrated micelles with cbB > ce, the B blocks were entangled with both hB matrix chains and B blocks of neighboring micelles. For MbB ≫ MhB, τ*conc of the concentrated micelles were longer than τCR and increased exponentially with cbB. For those micelles, τ*conc agreed well with those in a nonentangling matrix. However, with increasing MhB → MbB, τ*conc became insensitive to cbB and approached τCR. These results for the concentrated micelles were similar to those for homopolymer blends, suggesting that the CR mechanism affected the fast process of those micelles in the following way: For MbB ≫ MhB, the CR relaxation was rapid and entanglement between the matrix and the B blocks did not survive at time scales of τ*conc. Thus, at those time scales, the hB matrix behaved just as a diluent and the B blocks relaxed with a starlike (arm retraction) mechanism similar to that in the nonentangling matrix. On the other hand, for large MhB, the CR relaxation was retarded and the entanglement with the matrix still survived at time scales of τ*conc. For this case, the CR relaxation became a rate-determining step for the B block relaxation and led to the cbB-insensitive τ* (≅ τCR)." @default.
• W2092691569 created "2016-06-24" @default.
• W2092691569 creator A5064870756 @default.
• W2092691569 creator A5065801193 @default.
• W2092691569 creator A5088049480 @default.
• W2092691569 date "1996-01-01" @default.
• W2092691569 modified "2023-10-16" @default.
• W2092691569 title "Viscoelastic Relaxation of Styrene−Butadiene Diblock Copolymer Micellar Systems. 2. Behavior in Entangling, Long Polybutadiene Matrices" @default.
• W2092691569 cites W1994177855 @default.
• W2092691569 cites W1998813002 @default.
• W2092691569 cites W2003499863 @default.
• W2092691569 cites W2012191004 @default.
• W2092691569 cites W2019779058 @default.
• W2092691569 cites W2038974588 @default.
• W2092691569 cites W2053883951 @default.
• W2092691569 cites W2059196739 @default.
• W2092691569 cites W2061768452 @default.
• W2092691569 cites W2067051605 @default.
• W2092691569 cites W2073572480 @default.
• W2092691569 cites W2079730334 @default.
• W2092691569 cites W2089683152 @default.
• W2092691569 cites W2091887272 @default.
• W2092691569 cites W2093991967 @default.
• W2092691569 cites W30898119 @default.
• W2092691569 cites W4244333517 @default.
• W2092691569 cites W4247973432 @default.
• W2092691569 cites W4252591387 @default.
• W2092691569 doi "https://doi.org/10.1021/ma951250g" @default.
• W2092691569 hasPublicationYear "1996" @default.
• W2092691569 type Work @default.
• W2092691569 sameAs 2092691569 @default.
• W2092691569 citedByCount "14" @default.
• W2092691569 countsByYear W20926915692012 @default.
• W2092691569 countsByYear W20926915692017 @default.
• W2092691569 countsByYear W20926915692019 @default.
• W2092691569 crossrefType "journal-article" @default.
• W2092691569 hasAuthorship W2092691569A5064870756 @default.
• W2092691569 hasAuthorship W2092691569A5065801193 @default.
• W2092691569 hasAuthorship W2092691569A5088049480 @default.
• W2092691569 hasConcept C106487976 @default.
• W2092691569 hasConcept C11268172 @default.
• W2092691569 hasConcept C121040770 @default.
• W2092691569 hasConcept C121332964 @default.
• W2092691569 hasConcept C127413603 @default.
• W2092691569 hasConcept C147789679 @default.
• W2092691569 hasConcept C15744967 @default.
• W2092691569 hasConcept C15920480 @default.
• W2092691569 hasConcept C159985019 @default.
• W2092691569 hasConcept C184651966 @default.
• W2092691569 hasConcept C185592680 @default.
• W2092691569 hasConcept C186541917 @default.
• W2092691569 hasConcept C188027245 @default.
• W2092691569 hasConcept C192562407 @default.
• W2092691569 hasConcept C2776029896 @default.
• W2092691569 hasConcept C2777566558 @default.
• W2092691569 hasConcept C2780901341 @default.
• W2092691569 hasConcept C42360764 @default.
• W2092691569 hasConcept C521977710 @default.
• W2092691569 hasConcept C62520636 @default.
• W2092691569 hasConcept C77805123 @default.
• W2092691569 hasConcept C84114770 @default.
• W2092691569 hasConceptScore W2092691569C106487976 @default.
• W2092691569 hasConceptScore W2092691569C11268172 @default.
• W2092691569 hasConceptScore W2092691569C121040770 @default.
• W2092691569 hasConceptScore W2092691569C121332964 @default.
• W2092691569 hasConceptScore W2092691569C127413603 @default.
• W2092691569 hasConceptScore W2092691569C147789679 @default.
• W2092691569 hasConceptScore W2092691569C15744967 @default.
• W2092691569 hasConceptScore W2092691569C15920480 @default.
• W2092691569 hasConceptScore W2092691569C159985019 @default.
• W2092691569 hasConceptScore W2092691569C184651966 @default.
• W2092691569 hasConceptScore W2092691569C185592680 @default.
• W2092691569 hasConceptScore W2092691569C186541917 @default.
• W2092691569 hasConceptScore W2092691569C188027245 @default.
• W2092691569 hasConceptScore W2092691569C192562407 @default.
• W2092691569 hasConceptScore W2092691569C2776029896 @default.
• W2092691569 hasConceptScore W2092691569C2777566558 @default.
• W2092691569 hasConceptScore W2092691569C2780901341 @default.
• W2092691569 hasConceptScore W2092691569C42360764 @default.
• W2092691569 hasConceptScore W2092691569C521977710 @default.
• W2092691569 hasConceptScore W2092691569C62520636 @default.
• W2092691569 hasConceptScore W2092691569C77805123 @default.
• W2092691569 hasConceptScore W2092691569C84114770 @default.
• W2092691569 hasIssue "1" @default.
• W2092691569 hasLocation W20926915691 @default.
• W2092691569 hasOpenAccess W2092691569 @default.
• W2092691569 hasPrimaryLocation W20926915691 @default.
• W2092691569 hasRelatedWork W1836918941 @default.
• W2092691569 hasRelatedWork W1880283819 @default.
• W2092691569 hasRelatedWork W1970883354 @default.
• W2092691569 hasRelatedWork W2062247965 @default.
• W2092691569 hasRelatedWork W2066420315 @default.
• W2092691569 hasRelatedWork W2086323181 @default.
• W2092691569 hasRelatedWork W2091337967 @default.
• W2092691569 hasRelatedWork W2125637658 @default.
• W2092691569 hasRelatedWork W2167287036 @default.
• W2092691569 hasRelatedWork W2598351256 @default.
• W2092691569 hasVolume "29" @default.

• next