Matches in SemOpenAlex for { <https://semopenalex.org/work/W2092694648> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2092694648 endingPage "1376" @default.
- W2092694648 startingPage "1370" @default.
- W2092694648 abstract "The structure of poly[1-(trimethylsilyl)-1-propyne] (PTMSP) is distinct from other glassy polymers because of the presence of bulky side groups which obstruct the packing of polymer chains and allow extraordinarily high permeability of sorbed molecules. Molecular transport models traditionally applied to standard glassy polymers reach some limitations in the description of diffusion in PTMSP because of differences in the mechanism of sorption and diffusion. Analysis of sorption equilibria and permeability data measured for PTMSP is undertaken in an effort to elucidate the mechanism of mass transfer. Sorption equilibrium indicates that a multilayer adsorption mechanism can account for the isotherm data, and analysis of dynamics indicates that a multilayer surface diffusion model successfully characterizes the permeability measurement. A favorable comparison of values for the characterizing variables between PTMSP and other microporous materials generates further support for the assertion that this high free-volume glassy polymer can also be viewed as a microporous material." @default.
- W2092694648 created "2016-06-24" @default.
- W2092694648 creator A5034537641 @default.
- W2092694648 date "2001-02-07" @default.
- W2092694648 modified "2023-10-15" @default.
- W2092694648 title "Mechanism of Sorption and Diffusion in a High Free-Volume Polymer" @default.
- W2092694648 cites W1968291504 @default.
- W2092694648 cites W1970688432 @default.
- W2092694648 cites W1971948365 @default.
- W2092694648 cites W1972103123 @default.
- W2092694648 cites W1972233188 @default.
- W2092694648 cites W1980424919 @default.
- W2092694648 cites W1991136346 @default.
- W2092694648 cites W1993002209 @default.
- W2092694648 cites W1993300355 @default.
- W2092694648 cites W1995948215 @default.
- W2092694648 cites W2013572945 @default.
- W2092694648 cites W2016257712 @default.
- W2092694648 cites W2030267927 @default.
- W2092694648 cites W2038991434 @default.
- W2092694648 cites W2047335111 @default.
- W2092694648 cites W2067522049 @default.
- W2092694648 cites W2079443093 @default.
- W2092694648 cites W4211012608 @default.
- W2092694648 doi "https://doi.org/10.1021/ie000760i" @default.
- W2092694648 hasPublicationYear "2001" @default.
- W2092694648 type Work @default.
- W2092694648 sameAs 2092694648 @default.
- W2092694648 citedByCount "26" @default.
- W2092694648 countsByYear W20926946482013 @default.
- W2092694648 countsByYear W20926946482016 @default.
- W2092694648 countsByYear W20926946482017 @default.
- W2092694648 countsByYear W20926946482018 @default.
- W2092694648 countsByYear W20926946482019 @default.
- W2092694648 countsByYear W20926946482020 @default.
- W2092694648 crossrefType "journal-article" @default.
- W2092694648 hasAuthorship W2092694648A5034537641 @default.
- W2092694648 hasConcept C120882062 @default.
- W2092694648 hasConcept C121332964 @default.
- W2092694648 hasConcept C127413603 @default.
- W2092694648 hasConcept C147789679 @default.
- W2092694648 hasConcept C150394285 @default.
- W2092694648 hasConcept C159467904 @default.
- W2092694648 hasConcept C159985019 @default.
- W2092694648 hasConcept C178790620 @default.
- W2092694648 hasConcept C185592680 @default.
- W2092694648 hasConcept C188027245 @default.
- W2092694648 hasConcept C192562407 @default.
- W2092694648 hasConcept C2777197226 @default.
- W2092694648 hasConcept C41625074 @default.
- W2092694648 hasConcept C42360764 @default.
- W2092694648 hasConcept C521977710 @default.
- W2092694648 hasConcept C55493867 @default.
- W2092694648 hasConcept C58445606 @default.
- W2092694648 hasConcept C69357855 @default.
- W2092694648 hasConcept C86381522 @default.
- W2092694648 hasConcept C97355855 @default.
- W2092694648 hasConceptScore W2092694648C120882062 @default.
- W2092694648 hasConceptScore W2092694648C121332964 @default.
- W2092694648 hasConceptScore W2092694648C127413603 @default.
- W2092694648 hasConceptScore W2092694648C147789679 @default.
- W2092694648 hasConceptScore W2092694648C150394285 @default.
- W2092694648 hasConceptScore W2092694648C159467904 @default.
- W2092694648 hasConceptScore W2092694648C159985019 @default.
- W2092694648 hasConceptScore W2092694648C178790620 @default.
- W2092694648 hasConceptScore W2092694648C185592680 @default.
- W2092694648 hasConceptScore W2092694648C188027245 @default.
- W2092694648 hasConceptScore W2092694648C192562407 @default.
- W2092694648 hasConceptScore W2092694648C2777197226 @default.
- W2092694648 hasConceptScore W2092694648C41625074 @default.
- W2092694648 hasConceptScore W2092694648C42360764 @default.
- W2092694648 hasConceptScore W2092694648C521977710 @default.
- W2092694648 hasConceptScore W2092694648C55493867 @default.
- W2092694648 hasConceptScore W2092694648C58445606 @default.
- W2092694648 hasConceptScore W2092694648C69357855 @default.
- W2092694648 hasConceptScore W2092694648C86381522 @default.
- W2092694648 hasConceptScore W2092694648C97355855 @default.
- W2092694648 hasIssue "5" @default.
- W2092694648 hasLocation W20926946481 @default.
- W2092694648 hasOpenAccess W2092694648 @default.
- W2092694648 hasPrimaryLocation W20926946481 @default.
- W2092694648 hasRelatedWork W1966329677 @default.
- W2092694648 hasRelatedWork W1976412970 @default.
- W2092694648 hasRelatedWork W2081305936 @default.
- W2092694648 hasRelatedWork W2146413871 @default.
- W2092694648 hasRelatedWork W2150916988 @default.
- W2092694648 hasRelatedWork W2335574346 @default.
- W2092694648 hasRelatedWork W2360336875 @default.
- W2092694648 hasRelatedWork W2367813846 @default.
- W2092694648 hasRelatedWork W2373247340 @default.
- W2092694648 hasRelatedWork W2025707486 @default.
- W2092694648 hasVolume "40" @default.
- W2092694648 isParatext "false" @default.
- W2092694648 isRetracted "false" @default.
- W2092694648 magId "2092694648" @default.
- W2092694648 workType "article" @default.