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- W2092696586 abstract "The synthesis of 8,8a-trans-8-hydroxy-indolizidine 12 from (D,L)-pipecolinic acid by two alternative routes is described. The stereospecific decarbonylation of the bicyclic carboxyamide 9 promoted by diphenylphosphorazidate (DPPA) is the key step of our strategy. The bicyclic enamide 10 is described as a valuable intermediate in the synthesis of hydroxylated indolizidines." @default.
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- W2092696586 title "Amino acids as precursors to indolizidine alkaloids. DPPA-promoted decarbonylation of a bicyclic amino acid: An easy entry to hydroxylated indolizidines" @default.
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- W2092696586 doi "https://doi.org/10.1016/s0040-4039(00)78513-3" @default.
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