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- W2092696887 abstract "A computer program, CASPER, has been developed for the determination of the structure of polysaccharides composed of regular repeating-units. The program utilises the 13C-n.m.r. spectrum of the polysaccharide and information from sugar and methylation analyses. Based on the identity of the monosaccharides present in the repeating unit and the positions of the linkages, all possible permutations are constructed. With the aid of a database containing 13C-n.m.r. substituent shifts obtained from disaccharides, the spectra of the alternative structures are simulated and the best fit with the observed spectrum is selected. The program has been tested on two polysaccharides of known structures, for both of which the correct structure was selected." @default.
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- W2092696887 date "1987-10-01" @default.
- W2092696887 modified "2023-10-16" @default.
- W2092696887 title "Casper—a computerised approach to structure determination of polysaccharides using information from n.m.r. spectroscopy and simple chemical analyses" @default.
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- W2092696887 doi "https://doi.org/10.1016/0008-6215(87)80007-1" @default.
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