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- W2092706814 abstract "The preparation of the trans-dicarbonyls [OsX4(CO)2]− and [OsX4(CO)2]2− (X = Br, I) and of the mer-tricarbonyl [OsI3(CO)3]− as solid and stable salts with various cations is described. The compounds are characterized by spectra in the visible and IR region. The structures are affirmed by some chemical reactions and thermic rearrangements. Die Darstellung der trans-Dicarbonyle [OsX4(CO)2]− und [OsX4(CO)2]2− (X = Br, J) sowie des mer-Tricarbonyls [OsJ3CO)3]− im Form fester stabiler Salze mit verschiedenen Kationen wird beschrieben. Die Verbindungen werden durch die Spektren im sichtbaren und IR-Bereich charakterisiert. Anhand einiger chemischer Umsetzungen und thermischer Umlagerungen werden die Strukturen abgesichert." @default.
- W2092706814 created "2016-06-24" @default.
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- W2092706814 date "1975-03-01" @default.
- W2092706814 modified "2023-10-16" @default.
- W2092706814 title "Darstellung und eigenschaften von trans(mer)-halogenocarbonylosmaten(III) und -(II)" @default.
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- W2092706814 doi "https://doi.org/10.1016/s0022-328x(00)89829-0" @default.
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