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• W2092730065 abstract "A highly sensitive HPLC with direct fluorescent detection (λex = 235 nm, λem = 355 nm) was developed for Pb2+ and Cd2+ complexes with an aromatic polyaminocarboxylate, 1-(4-aminobenzyl)ethylenediamine-N,N,N′,N′-tetraacetate as a pre-column derivatizing agent. A reversed phase partition column pretreated by a cationic surfactant was employed. Although this ligand forms thermodynamically stable complexes with various metal ions, only peaks of Pb2+ and Cd2+ were detected with the ligand-centered emission in the HPLC due to the emissive activity and kinetic stability in the dissociation reaction. The detection limits obtained were 1.5 × 10−8 and 3.3 × 10−9 mol l−1 for Pb2+ and Cd2+, respectively." @default.
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• W2092730065 date "2006-02-01" @default.
• W2092730065 modified "2023-09-25" @default.
• W2092730065 title "Direct fluorescence detection of Pb2+ and Cd2+ by high-performance liquid chromatography using 1-(4-aminobenzyl)ethylenediamine-N,N,N′,N′-tetraacetate as a pre-column derivatizing agent" @default.
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• W2092730065 doi "https://doi.org/10.1016/j.chroma.2005.11.085" @default.
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