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- W2092752673 abstract "The aggregation states of Mn2+ in KBr Mn2+ doped crystals are investigated using optical techniques. Excitation and luminescence spectra as well as lifetimes are obtained as a function of temperature of different crystals. It is demonstrated that at least three different Mn2+ precipitates are formed inside the KBr. Two of them contain MnBr64- units with slightly distorted octahedral symmetries, while the third one involves two non-equivalent tetrahedral MnBr42- units. These centers exhibit a broad green luminescence band. Die Erscheinungsformen von Mn2+ in dotierten KBr:Mn2+-Kristallen werden mit optischen Methoden untersucht. Anregungs- und Lumineszenzpektren und Lebendauern als Funktion der Temperatur verden an verschiedenen Kristallen gemessen. Es zeigt sich, daß mindestens drei verschiedene Mn2+-Aggregate im KBr auftreten. Zwei von ihnen enthalten MnBr64−-Einheiten mit leicht gestörter oktaedrischer Symmetrie, das dritte ist mit zwei inäquivalenten tetraedrischen MnBr42−-Einheiten vernüpft. Diese Zentren zeigen ein breites, grünes Lumineszenzband." @default.
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- W2092752673 date "1992-08-01" @default.
- W2092752673 modified "2023-10-04" @default.
- W2092752673 title "Study of Precipitated Phases in Mn2+ Singly Doped KBr Crystals by Optical Spectroscopy and EPR" @default.
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- W2092752673 doi "https://doi.org/10.1002/pssb.2221720223" @default.
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