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- W2092772059 abstract "13C NMR chemical shifts for some 3-heterosubstituted 2-methylpropenes are reported. The α-methylene chemical shifts show excellent linear correlations with the corresponding data for some substituted carbonyl compounds (propanones, methyl acetates and N,N-diethylacetamides). Their estimated intramolecular interaction shifts are indicative of electronic interactions between the heteroatom and the ethylenic double bond. The sp2 carbon shifts calculated by Dorman et al.'s method, taking a proposed set of βσ and βπ parameters, are in close agreement with the experimental values. Neither the α-methylene nor the olefinic carbon chemical shifts correlate well with the usual electronic and steric parameters of the substituents." @default.
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- W2092772059 date "1992-05-01" @default.
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- W2092772059 title "Carbon-13 NMR chemical shift substituent effects 8—3-monosubstituted 2-methylpropenes" @default.
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- W2092772059 doi "https://doi.org/10.1002/mrc.1260300513" @default.
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