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- W2092790295 abstract "An effective formal total synthesis of (+)-12-deoxyscalarolide is described, starting from natural manool. Two alternative reaction schemes have been investigated for the synthesis of the tetra-carbocyclic key intermediate (–)-methyl 17-oxo-24-norscalaran-25-oate. The unsaturated lactonic ring is then created from this ester in three steps to afford, in high yield, the (–)-scalar-16-en-25,24-olide which is easily isomerised under basic conditions to (+)-12-deoxyscalarolide." @default.
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- W2092790295 date "1990-01-01" @default.
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- W2092790295 title "Formal total synthesis of (+)-12-deoxyscalarolide" @default.
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- W2092790295 doi "https://doi.org/10.1039/p19900002545" @default.
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