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- W2092792403 abstract "We present a comparison of theoretical and experimental rate coefficients for the reactions of H3+, HCO+, H−, C+ and O+ with HCN, and H3+ with HCl, over the temperature range 205–540 K. The theoretical results are obtained using an adiabatic capture theory which is selective in the initial rotational states of the reacting dipolar molecules. The experiments were performed using a variable-temperature SIFT apparatus. For the H3+ and HCO+ proton transfer reactions in particular, there is excellent agreement between theory and experiment, with the rate coefficients increasing sharply with decreasing temperature." @default.
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- W2092792403 date "1985-09-01" @default.
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- W2092792403 title "Temperature dependence of rate coefficients for reactions of ions with dipolar molecules" @default.
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- W2092792403 doi "https://doi.org/10.1016/0009-2614(85)80425-5" @default.
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