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- W2092804452 abstract "We have analyzed the hysteretic properties of thermal and pressure induced low spin (LS)↔high spin (HS) phase transition of a 3-D spin crossover (SCO) nanostructure when the cluster architecture is progressively changed from a cubic to a thin film. For solving the 3-D Ising-like Hamiltonian, the Monte Carlo metropolis technique is used, with the edge molecules trapped in HS state. The role of short- and long-range interactions on the SCO cooperativity has been investigated as well. The obtained results show that the cooperativity of a 3-D SCO system, characterized by the same number of molecules and the same interactions strength are strongly affected when going from a cubic 3-D to thin-film architecture. These results are discussed in terms of surface effects." @default.
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- W2092804452 date "2014-11-01" @default.
- W2092804452 modified "2023-10-10" @default.
- W2092804452 title "Analysis of Architecture Effect on Hysteretic Behavior of 3-D Spin Crossover Nanostructures" @default.
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- W2092804452 doi "https://doi.org/10.1109/tmag.2014.2322878" @default.
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