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- W2092861168 abstract "In the title compound, [MnCl2(C16H15N5)(CH4O)], the manganese(II) cation is six-coordinate, forming a distorted octahedral configuration with bis(1H-benzimidazol-2-ylmethyl)amine (IDB) serving as a neutral tridentate chelating ligand. Two imine and one amine N atoms from IDB and one Cl anion form the equatorial plane. The two axial positions are occupied by the methanol O atom and the other Cl anion. By a combination of two N–H⋯Cl and one O—H⋯Cl hydrogen bonds, molecules are linked into a three-dimensional network which is strengthened by weak C—H⋯π and π–π interactions [interplanar spacing = 3.343 (1) A, ring-centroid separation = 3.728 (3) A, corresponding to a ring offset of 1.650 (1) A]." @default.
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- W2092861168 date "2007-11-23" @default.
- W2092861168 modified "2023-09-25" @default.
- W2092861168 title "[Bis(1H-benzimidazol-2-ylmethyl)amine-κ3N,N′,N′′]dichlorido(methanol)manganese(II)" @default.
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- W2092861168 doi "https://doi.org/10.1107/s1600536807058783" @default.
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