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- W2092880366 abstract "Abstract A tris (2-aminoethyl)amine (tren) copper(II) complex with a coordinated 4-aminopyridine (4-APy) ligand was synthesized and characterized. Single crystal X-ray diffraction study reveals that there are two slightly different cations and four perchlorate anions present in an asymmetric unit. The coordination geometry of both Cu(II) centers are nearly identical and close to trigonal bipyramidal with three terminal amine nitrogen atoms forming the equatorial plane, while the tertiary nitrogen atom and the pyridine nitrogen atom from 4-APy occupy the apical positions. Of the two different cations, one shows an outer-sphere, bridged copper dimer with the nitrogen atom N(6) from 4-APy and the terminal amino nitrogen atom N(3) linked together by hydrogen bonds N(6)−H.N(3a) and N(3).H−N(6a) (1 − x − y, 1 − z). Magnetic and spectroscopic data support the outer-sphere, bridged dimeric structure. The title complex, Cu(tren)(4-Apy)](ClO4)2, crystallizes in the monoclinic space group P21/n with cell parameters a = 8.150(1), b = 33.854(2), c = 14.810(1) Å, β = 90.00(1)°, V = 3967(2) Å3 and Z = 8. The structure was refined by full-matrix least-squares to R = 0.065 and Rw = 0.088 with 3880 reflections having F > 6[sgrave](F)." @default.
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- W2092880366 date "1998-05-01" @default.
- W2092880366 modified "2023-09-25" @default.
- W2092880366 title "CRYSTAL STRUCTURE AND SPECTROSCOPIC STUDIES OF TRIS(2-AMINOETHYL)AMINE COPPER(II) COMPLEXES WITH 4-AMINOPYRIDINE" @default.
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- W2092880366 doi "https://doi.org/10.1080/00958979808022889" @default.
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