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• W2092892656 abstract "1H and (19)F pulsed gradient spin-echo (PGSE) diffusion studies on cationic mono- and trinuclear iridium complexes containing the PHOX chiral P,N-auxiliary (S)-4-tert-butyl-2-[2-(di-o-tolylphosphino)phenyl]-4,5-dihydrooxazole with the anions BF(4)(-), PF(6)(-), OTf(-), B(C(6)F(5))(4)(-), and BArF(-) in methanol, chloroform, methylene chloride, and 1,2-dichloroethane are reported. In chloroform, the anion and cation within each salt afford almost the same, relatively small, diffusion constant (D-value) suggesting strong ion-pairing. In methanol, the D-value for the cation is the same in the five mononuclear salts, suggesting that the cation is moving independently of the anion (no ion-pairing). In methylene chloride and 1,2-dichloroethane the diffusion data suggest a mixed picture for the five anions. While the smaller BF(4)(-), PF(6)(-), and OTf(-) anions do not affect the translation of the cations, the larger boron-based anions B(C(6)F(5))(4)(-) and BArF(-) clearly slow the motions of the cations. However, it would seem that for all five anions there is some--but not complete--ion pairing in these two solvents." @default.
• W2092892656 created "2016-06-24" @default.
• W2092892656 creator A5031172461 @default.
• W2092892656 creator A5037478989 @default.
• W2092892656 date "2003-02-22" @default.
• W2092892656 modified "2023-10-18" @default.
• W2092892656 title "¹H and ¹⁹F PGSE Diffusion Studies on Iridium PHOX Complexes: Counterion and Solvent Dependences" @default.
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• W2092892656 doi "https://doi.org/10.1021/ic0206600" @default.
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