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- W2092923471 abstract "Shifts of the Si 2p, O 1s, and N 1s core-level spectra with the O or N content x for amorphous (a-) ${mathrm{SiO}}_{mathit{x}}$ and ${mathrm{SiN}}_{mathit{x}}$ films were examined by means of the effective-charge-analysis (ECA) model, in which the averaged partial charge ${mathit{P}}_{mathit{M}}$(x) (M=Si, O, or N) on a given atom is expressed as a function of x, by using Sanderson's electronegativity results and the random-bonding model (RBM). The effective Si 2p binding energy ${mathit{E}}_{mathit{B}}$(Si 2p) was found to be linearly related to ${mathit{P}}_{mathrm{Si}}$(x) per single bond, ${mathit{E}}_{mathit{B}}$(Si 2p)=10.2${mathit{P}}_{mathrm{Si}}$(x)+99.3, independent of sample type. This equation predicts that addition of a unit of positive charge onto a Si atom shifts the Si 2p core level downward by 2.55 eV. Furthermore, the ECA model showed that spacing of the Si 2p lines due to five Si(${mathrm{Si}}_{4mathrm{ensuremath{-}}mathit{n}}$${mathit{M}}_{mathit{n}}$) (M=O or N) bonding units based on the RBM decreases with increasing n, in contrast to an assumption made by many workers. The evaluated negative partial charge, ${mathit{P}}_{mathrm{O}}$(x) or ${mathit{P}}_{mathrm{N}}$(x), on an O or N atom is found to decrease with increasing x, and the observed ${mathit{E}}_{mathit{B}}$(O 1s) and ${mathit{E}}_{mathit{B}}$(N 1s) are also linearly related to ${mathit{P}}_{mathrm{O}}$(x) and ${mathit{P}}_{mathrm{N}}$(x), respectively. Both the O 1s and N 1s core levels were shown to shift downward by around 1.2 eV as a unit negative charge is subtracted from the O and N atom." @default.
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- W2092923471 date "1992-11-15" @default.
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- W2092923471 title "Analysis of photoemission in amorphous<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>SiO</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=italic>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>SiN</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=italic>x</mml:mi></…" @default.
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- W2092923471 doi "https://doi.org/10.1103/physrevb.46.12478" @default.
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