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- W2092949001 abstract "Mutual ligand arrangement in binuclear lanthanoid complexes of the type [Gu2Ln(μ-H)]2, [Gu2Ln(μ-Cl)]2, and Gu2Ln(μ-Cl)2Li(THF)2, where Gu is a substituted guanidinato ligand, is quantitatively analyzed based on the ligand solid angle approach. In complexes of Nd, Sm, and Gd the Gu ligands shield up to 87% of the metal and the bidentate ligands on opposite metal centers are in the eclipsed arrangement; in complexes of lanthanoids with smaller ionic radii Y, Yb, and Lu the Gu ligands shield over 88.3% of the metal surface and their staggered conformation is observed. The ligand solid angle approach is illustrated and its application to describing multidentate ligands is demonstrated." @default.
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- W2092949001 date "2007-05-11" @default.
- W2092949001 modified "2023-09-23" @default.
- W2092949001 title "Dependence of the mutual ligand arrangement in guanidinate complexes of lanthanoids on the ligand solid angles" @default.
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- W2092949001 doi "https://doi.org/10.1080/00958970600987933" @default.
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