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- W2093005290 abstract "TheG0u+(61P1)–X0G+excitation and fluorescence spectra of Hg2van der Waals molecules, produced in a pulsed free-jet supersonic expansion beam crossed with a pulsed dye-laser beam, were studied using Ar as the carrier gas. A well-resolved vibrational structure of theG0u+←X0g+excitation spectrum was recorded, as well as the isotopic structures of the vibrational components. A Condon internal diffraction pattern in theG0u+→X0g+fluorescence band, emitted upon the selective excitation of the v′ = 39 vibrational component, was also observed and confirmed the assignments derived from the analysis of the isotopic structure. Analyses of the spectra yielded molecular constants for both states, as well as information on the ground state potential energy curve. The results are compared with those obtained from other experiments and from theoretical calculations." @default.
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- W2093005290 date "1997-08-01" @default.
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- W2093005290 title "TheG0u+(61P1)–X0G+Excitation and Fluorescence Spectra of Hg2Excited in a Supersonic Jet" @default.
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- W2093005290 doi "https://doi.org/10.1006/jmsp.1997.7345" @default.
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